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Particulate Matter (PM) legislation for gasoline engines and the introduction of gasoline/ethanol blends, make it important to know the effect of fuel composition on PM emissions. Tests have been conducted with fuels of known composition in both a single-cylinder engine and V8 engine with a three-way catalyst. The V8 engine used an unleaded gasoline (PURA) with known composition and distillation characteristics as a base fuel and with 10% by volume ethanol. The single-cylinder engine used a 65% iso-octane - 35% toluene mixture as its base fuel. The engines had essentially the same combustion system, with a centrally mounted 6-hole spray-guided direct injection system. Particle size distributions were recorded and these have also been converted to mass distributions. Filter samples were taken for thermo-gravimetric analysis (TGA) to give composition information. Both engines were operated at 1500 rpm under part load.

A study has been undertaken with a single-cylinder engine, based on the Mitsubishi GDi combustion system, that has the option of either port injection or direct injection. Tests have been undertaken with pure fuel components (methane, iso-octane, toluene and methanol), and a representative gasoline that has also been tested with the addition of 10% methanol and 10% ethanol. The volumetric efficiency depends both on the fuel and its time and place of injection. For stoichiometric operation with unleaded gasoline, changing from port injection to direct injection led to a 9% increase in volumetric efficiency, which was improved by a further 3% when 10% methanol was blended with the gasoline. The improvements in volumetric efficiency will be used to quantify the extent of charge cooling by fuel evaporation, and these will be compared with predictions assuming the maximum possible level of fuel evaporation.

Model M15 gasoline fuels have been created from pure fuel components, to give independent control of volatility, the heavy end content and the aromatic content, in order to understand the effect of the fuel properties on Gasoline Direct Injection (GDI) fuel spray behaviour and the subsequent particulate number emissions. Each fuel was imaged at a range of fuel temperatures in a spray rig and in a motored optical engine, to cover the full range from non-flashing sprays through to flare flashing sprays. The spray axial penetration (and potential piston and liner impingement), and spray evaporation rate were extracted from the images. Firing engine tests with the fuels with the same fuel temperatures were performed and exhaust particulate number spectra captured using a DMS500 Mark II Particle Spectrometer.

A model for the evaporation of a multi-component fuel droplet is presented that takes account of temperature dependent fuel and vapour properties, evolving droplet internal temperature distribution and composition, and enhancement to heat and mass transfer due to droplet motion. The effect on the internal droplet mixing of non-ideal fluid diffusion is accounted for. Activity coefficients for vapour-liquid equilibrium and diffusion coefficients are determined using the UNIFAC method. Both well-mixed droplet evaporation (assuming infinite liquid mass diffusivity) and liquid diffusion-controlled droplet evaporation (iteratively solving the multi-component diffusion equation) have been considered. Well-mixed droplet evaporation may be applicable with slow evaporation, for example early gasoline direct injection; diffusion-controlled droplet evaporation must be considered when faster evaporation is encountered, for example when injection is later, or when the fuel mixture is non-ideal.