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Dual-fuel technology has the potential to offer significant improvements in the emissions of carbon dioxide from light-duty compression ignition engines. The dual-fuel (diesel/natural gas) concept represents a possible solution to reduce emissions from diesel engines by using natural gas (methane) as an alternative fuel. Methane was injected in the intake manifold while the diesel oil was injected directly into the engine. The present work describes the results of a numerical study on combustion process of a common rail diesel engine supplied with natural gas and diesel oil. In particular, the aim is to study the effect of increasing methane concentration at constant injected diesel amount on both pollutant emissions and combustion evolution. The study of dual-fuel engines that is carried out in this paper aims at the evaluation of the CFD potential, by a 3-dimensional code, to predict the main features of this technology.