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In view of the new emission regulations seeking to lower the particle cut-off size down to the current 23 nm, an extensive comprehension on the nature of sub-23 nm particles is crucial. In this regard, a new challenge lies ahead considering an even more massive use of biofuels. The objective of this research study was to characterize the sub-23 nm particles and to evaluate their volatile organic fraction (VOF) from a high performance, 1.8 L gasoline direct injection (GDI) engine under the Worldwide harmonized Light vehicles Test Cycle (WLTC). Particle emissions were measured through an Engine Exhaust Particle Sizer (EEPS) capable of particle sizing and counting in the range 5.6 - 560 nm. The sampling and conditioning were performed by both a single diluter and the Dekati Engine Exhaust Diluter (DEED) a Particle Measurement Programme (PMP) compliant sample conditioning system.

Methane supply in diesel engines operating in dual fuel mode has demonstrated to be effective for the reduction of particulate matter and nitric oxides emissions from this type of engine. In particular, methane is injected into the intake manifold to form a premixed charge with air, while a reduced amount of diesel oil is still directly injected to ignite the mixture inside the cylinder. As a matter of fact, the liquid fuel burns following the usual diffusive combustion, so activating the gaseous fuel oxidation in a premixed flame. Clearly, the whole combustion process appears to be more complex to be described in a CFD simulation, mainly because it is not always possible to select in the 3-dimensional codes a different combustion model for each fuel and, also, because other issues arise from the interaction of the two fuels.

Growing concerns about the emissions of internal combustion engines have forced the adoption of aftertreatment devices to reduce the adverse impact of diesel engines on health and environment. Diesel particulate filters are considered as an effective means to reduce the particle emissions and comply with the regulations. Research activity in this field focuses on filter configuration, materials and aging, on understanding the variation of soot layer properties during time, on defining of the optimal strategy of DPF management for on-board control applications. A model was implemented in order to simulate the filtration and regeneration processes of a wall-flow particulate filter, taking into account the emission characteristic of the engine, whose architecture and operating conditions deeply affect the size distribution of soot particles.

In this work, a boosted single-cylinder spark ignition port-fuel injection optical engine was used for the experimental activity. Firstly, it was equipped with a four-valve head of a commercial turbocharged multi-cylinder engine. Then a prototype engine head with flush installed intake valves was tested. The effect of the different head geometry was evaluated in closed intake valves fuel injection condition. High spatial resolution cycle-resolved digital imaging was used to characterise the flame propagation. Moreover, the presence of diffusion-controlled flames near the valves and on the cylinder walls was investigated. These flames induced the formation of unburned hydrocarbons and soot particles. The spatial distribution and temporal evolution of soot were evaluated by the two colour pyrometry. The prototype configuration showed higher combustion process efficiency than the standard one inducing a little increase in performance and a slight reduction in carbon oxides emissions.

Data decomposition techniques have become a standard approach for the analysis of 2D imaging data originating from optically accessible internal combustion engines. In particular, the method of Proper Orthogonal Decomposition (POD) has proven to be a valuable tool for the evaluation of cycle-to-cycle variability based on luminous combustion imaging and particle image velocimetry (PIV) measurements. POD basically permits to characterize the dominant structures of the process under consideration. Recently, an alternative procedure based on Independent Component Analysis (ICA) has been introduced in the engine field. Unlike POD, the method of ICA identifies the patterns corresponding to physical processes that are statistically independent. In this work, a Group-ICA approach is applied to 2D cycle-resolved images of the luminosity emitted by the combustion process. The analysis is meant to characterize cyclic variability of a port fuel injection spark ignition (PFI SI) engine.

Nowadays, the regulation regards only the particles larger than 23 nm. The attention is shifting towards the sub-23 nm particles because of their large presence at the exhaust of the modern engines and their negative impact on human health. The main challenge of the regulation of these particles is the definition of a proper procedure for their measure. The nature of the sub-23 nm particles is not well understood, and their measure is strongly affected by the sampling conditions leading to not reliable measure. The aim of this paper is to provide information on the emissions of sub-23 nm particles from GDI vehicles/engines. At the same time, the presence of volatiles, which mainly contribute to the formation of sub-23 nm particles, was evaluated and the effect of sampling conditions was investigated. The analysis was performed on a 1.8L GDI powered vehicle, widely used both in North America and Europe, and a 4-cylinder GDI engine, whose features are similar to those of the vehicle.

Homogeneous Charge Compression Ignition (HCCI) combustion was applied to a transparent diesel engine equipped with high pressure Common Rail (CR) injection system. By means of CR system the quantity of fuel was split into five injections per cycle. Combined measurements, based on digital imaging and spectroscopic techniques, were applied to follow the evolution of HCCI combustion process with high temporal and spatial resolution. Digital imaging allowed to analyse injection and combustion phases. Broadband ultraviolet - visible extinction spectroscopy (BUVES) and flame emission measurements were carried out to evaluate the presence of radicals and species such as HCO, OH, CH, and CO. In particular, BUVES measurements were performed to follow fuel oxidation, and pollutant formation and oxidation. During injection and cool combustion, bands of aromatic compounds and alkyl peroxides, indicating fuel decomposition, and hydrogen peroxides were detected.

The match among the increasing performance demands and the stringent requirements of emissions and the fuel consumption reduction needs a strong evolution in the two-wheel vehicle technology. In particular, many steps forward should be taken for the optimization of modern small motorcycles and scooters at low engine speeds and high loads. To this aim, detailed understanding of thermo-fluid dynamic phenomena that occur in the combustion chamber is fundamental. In this work, low-cost solutions are proposed to optimize ported fuel injection spark ignition (PFI SI) engines for two-wheel vehicles. The solutions are based on the change of phasing and on the splitting of the fuel injection in the intake manifold. The experimental activities were carried out in the combustion chamber of a single-cylinder 4-stroke optical engine fuelled with European commercial gasoline. The engine was equipped with a four-valve head of a commercial scooter engine.

In this paper we report how optical techniques were applied in the cylinder of an optically accessible engine equipped with latest-generation EURO V diesel engine head. The injection strategy with high percentage of EGR, characteristic of real engine operating point, was adopted. In particular, the combustion behavior at 1500 rpm\2 bar BMEP was investigated. Alternative diesel fuels were used. In particular, rapeseed methyl ester (RME) and gas to liquid (GTL) were selected as representative of 1st and 2nd generation alternative diesel fuel, respectively. Combustion analysis was carried out in the engine combustion chamber by means of visible digital imaging. These measurements helped to analyze the chemical and physical events occurring during the mixture preparation and the combustion development. Ultraviolet (UV) digital imaging was also performed and the presence of characteristic radical, like OH, in the various phases of combustion was detected as well.

In the last years, there has been an increasing concern on the emission of ultrafine particles in the atmosphere. A detailed study of formation and oxidation of these particles in the environment of the diesel cylinder presents many experimental difficulties due to the high temperatures, pressures and extremely reactive intermediate species. In this paper, in order to follow the different phases of diesel combustion process, high temporal and spatial resolution optical techniques were applied in the optically accessible chamber of diesel engine, at 2000 rpm and A/F=80:1 and 60:1. Simultaneous extinction, scattering and flame chemiluminescence measurements from UV to visible were carried out, in order to study the diesel combustion process from the droplet ignition to the formation of soot, through the growth of its precursors.

Multidimensional simulation of the soot formation process in a diesel engine is realised exploiting quantitative measurements of the soot volume fraction and diameter obtained by optical techniques. Broadband extinction and scattering measurements are performed on an optically accessible 4-stroke engine where a forced air motion allows a strong prevalence of the premixed stage of combustion with respect to the non-premixed one. Two semi-empirical models for soot formation are tested in the numerical simulation, which is performed using a customized version of the KIVA-3 code. The need of furnishing coherent values of the soot particles density and mean diameter to the one of the two models requiring this kind of information, is highlighted and demonstrated to be crucial in avoiding over-prediction of the soot concentration.

Non-intrusive diagnostic techniques based on broadband (190-550 nm) extinction and scattering spectroscopy were applied to undiluted exhaust Common Rail (CR) diesel engine. The influence of engine speed and load on soot mass concentration, size distribution of emitted particles and NOx concentration was analysed. NOx concentration was evaluated by “in situ” ultraviolet-visible absorption measurements and compared with those obtained by conventional analyser. The extinction and scattering spectra were compared with those evaluated by the Lorenz-Mie model for spherical particles in order to retrieve the size, the number concentration of the emitted particles and particulate mass.

Spectroscopic measurement and high speed visualization were used in single cylinder, four-stroke DI diesel engine, optically accessible. It was equipped with a four valves head and fully flexible electronic controlled ‘Common Rail’ injection system. The effect of pilot and main injection on combustion process was evaluated. Mixing formation, autoignition and soot formation process were analyzed by broadband ultraviolet-visible flame emission spectroscopy and high-speed digital imaging. The autoignition phase occurred near the tip of the jet and was characterized by strong presence of OH radicals for both investigated conditions The presence of C2 and OH radicals strongly characterized CR diesel combustion process during soot formation and evolution. In particular, high presence of OH concentration for the whole process from the autoignition to the soot formation and successive phases contributes to lower soot levels.

Diesel combustion process was studied and characterized by digital imaging and ultraviolet-visible flame emission, extinction and scattering spectroscopy. Optical measurements were applied to a transparent diesel engine, realized by modifying a single cylinder, air-cooled, 4-stroke diesel engine by means of an external combustion chamber on the top of the engine, connected to the main chamber by a tangential passage. Diesel engine was equipped with a fully flexible electronic controlled ‘Common Rail’ injection system. Measurements were performed at 1000 rpm engine speed for two typical injection strategies. The first one consisted of a main injection in order to compare the results with those ones obtained by conventional injection system operating at low pressure. The other one was based on a pilot and main injection that is typical of current direct injection diesel engines.

This paper aims to correlate the in-cylinder soot formation and the exhaust particle emissions for different methods of gasoline/ethanol fueling in spark ignition engine. In particular, the engine was fueled with gasoline and ethanol separately and not, in this latter case both blended (E30) and dual fueled (EDF). For E30 the bend was direct injected and for EDF, the ethanol was injected in the combustion chamber and the gasoline into the intake duct. For both the injection configurations, the same percentage of ethanol in gasoline was supplied: 30%v/v. The measurements were carried out at 2000 and 4000 rpm, under full load, and stoichiometric condition, in small single cylinder optical engine. 2D-digital imaging was performed to follow the combustion process with a high spatial and temporal resolution through a full-bore optical piston. The two-color pyrometry was applied for the analysis of the in cylinder soot formation in the combustion chamber.

Internal combustion engines performance greatly depends on the air-fuel mixture formation and combustion processes. In gasoline direct injection (GDI) engines, in particular, the impact of the liquid spray on the piston or cylinder walls is a key factor, especially if mixture formation occurs under the so-called wall-guided mode. Impact causes droplets rebound and/or deposition of a liquid film (wallfilm). After being rebounded, droplets undergo what is called secondary atomization. The wallfilm may remain of no negligible size, so that fuel vapor rich zones form around it leading to so-called pool-flames (flames placed in the piston pit), hence to unburned hydrocarbons (HC) and particulate matter (PM) formation. A basic study of the spray-wall interaction is here performed by directing a multi-hole GDI spray against a real shape engine piston, possibly heated, under standard air conditions.

The aim of the present work is to provide further guidance into better understanding the production mechanisms of soot emissions in Spark-Ignition SI engines fueled with compressed natural gas. In particular, extensive experimental investigations were designed with the aim to isolate the contribution of the fuel from that of lubricant oil to particle emissions. This because the common thought is that particulate emerging from the engine derives mainly from fuel, otherwise the contribute of lubricant oil cannot be neglected or underestimated, especially when the fuel itself produces low levels of soot emissions, such as in the case of premixed natural gas. The fuel-derived contribution was studied by analyzing the influence that natural gas composition has on soot emitted from a single cylinder Spark-Ignition (SI) engine. To achieve this purpose, methane/propane mixtures were realized and injected into the intake manifold of a Single-Cylinder SI engine.

In this paper, the effect of the oxygen addition on engine performance and exhaust emissions was investigated. The experimental study was carried out in a small single-cylinder PFI SI four-stroke engine. The addition of the 5% vol and 10% vol of oxygen was performed in the intake duct. Typical urban driving operating conditions were investigated. The engine emissions were characterized by means of gaseous analyzers and a smokemeter. Particle size distribution function was measured in the size range from 5.6 to 560 nm by means of an Engine Exhaust Particle Sizer (EEPS). An improvement in terms of engine power output, without BSFC penalty, and HC emissions with oxygen addition was observed at all the investigated operating conditions. On the other hand, NOx and PM emissions increase.

This paper deals with the combustion behavior and exhaust emissions of a small compression ignition engine modified to operate in diesel/methane dual fuel mode. The engine is a three-cylinder, 1028 cm3 of displacement, equipped with a common rail injection system. The engine is provided with the production diesel oxidation catalyst. Intake manifold was modified in order to set up a gas injector managed by an external control unit. Experiments were carried out at different engine speeds and loads. For each engine operating condition, the majority of the total load was supplied by methane while a small percentage of the load was realized using diesel fuel; the latter was necessary to ignite the premixed charge of gaseous fuel. Thermodynamical analysis of the combustion phase was performed by in-cylinder pressure signal. Gas emissions and particulate matter were measured at the exhaust by commercial instruments.

The use of oxygenated and renewable fuels is nowadays a widespread means to reduce regulated pollutant emissions produced by internal combustion engines, as well as to reduce the greenhouse impact of transportation. Besides PM, NOx and HC emissions, also the size distribution of particles emitted at the engine exhaust represent meaningful information, considering its adverse effects on the environment and human health. In this work, the results of a comprehensive investigation on the combustion characteristics and the exhaust emissions of a GDI high performance engine, fuelled with pure bio-ethanol and European gasoline, are shown. The engine is a 4-cylinder, 4-stroke, 1750 cm₃ displacement, and turbocharged. The engine was operated at different speed/load conditions and two fuel injection strategies were investigated: homogeneous charge mode and stratified charge mode.