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This paper presents the results of a three city survey designed to determine the relative frequency of illumination of vehicle on-board diagnostic (OBD) malfunction indicator lights (MIL) on 2001 and later model year vehicles. The survey was conducted in a Canadian market, Regina, and two U.S. markets, Minneapolis and Denver, to assess claims that the presence of methycyclopentadienyl manganese tricarbonyl (MMT®) in gasoline causes the failure of technology necessary to meet stringent Tier 2 emission standards applicable in North America. The results of the survey do not support the claim that MMT® is incompatible with the effective functioning of the advanced vehicle emission technology necessary to meet Tier 2 emission standards. The results substantiate that the performance of the most advanced vehicles operating on gasoline containing MMT® is not materially different from the performance of comparable vehicles operating on gasoline that does not contain MMT®.

Mobile source emissions standards are becoming more stringent and particulate emissions from gasoline direct injection (GDI) engines represent a particular challenge. Gasoline particulate filter (GPF) is deemed as one possible technical solution for particulate emissions reduction. In this work, a study was conducted on eight formulations of lubricants to determine their effect on GDI engine particulate emissions and GPF performance. Accelerated ash loading tests were conducted on a 2.4L GDI engine with engine oil injection in gasoline fuel by 2%. The matrix of eight formulations was designed with changing levels of sulfated ash (SASH) level, Zinc dialkyldithiophosphates (ZDDP) level and detergent type. Comprehensive evaluations of particulates included mass, number, size distribution, composition, morphology and soot oxidation properties. GPF performance was assessed through filtration efficiency, back pressure and morphology.

In July 2002, the Alliance of Automobile Manufacturers, the Association of International Automobile Manufacturers and the Canadian Vehicle Manufacturers Association released the results of a 6-year, two-part vehicle fleet test program to determine the effects of methyl-cyclopentadienyl manganese tricarbonyl (MMT®*) on vehicles equipped with state of the art emission control systems. Analysis of the data reports from this study shows that all of the vehicles met applicable emission standards, even though the fleet accumulated mileage under very severe conditions that accelerate degradation of vehicle emission control systems in excess of that expected from actual vehicle mileage. The study also demonstrated that gasoline-containing MMT had no adverse impact on vehicular emission control equipment.

SAE Paper 2002-01-2894 entitled, “The Impact of MMT Gasoline Additive on Exhaust Emissions and Fuel Economy of Low Emission Vehicles (LEV)” presents discussion and conclusions concerning the emissions from vehicles that accumulated mileage on gasoline with and without the fuel additive, methylcyclopentadienyl manganese tricarbonyl (or MMT®). Although the authors of the paper express concern about use of MMT®, the data on which the authors rely are consistent with the results and conclusions from prior evaluations of MMT® which have found that MMT® is compatible with effective emission control system operation (1,2,3). All vehicles tested in the study met the emission standards for all pollutants that apply to the test vehicles in-use and analysis of the data show MMT® had no effect on fuel economy.

Because of the increased use of gasoline direct engine (GDI) in the automobile industry, there is a significant need to control particulates from GDI engines based on emission regulations. One potential technical approach is the utilization of a gasoline particulate filter (GPF). The successful adoption of this emission control technology needs to take many aspects into consideration and requires a system approach for optimization. This study conducted research to investigate the impact of vehicle driving cycles, fuel properties and catalyst coating on the performance of GPF. It was found that driving cycle has significant impact on particulate emission. Fuel quality still plays a role in particulate emissions, and can affect the GPF performance. Catalyzed GPF is preferred for soot regeneration, especially for the case that the vehicle operation is dominated by congested city driving condition, i.e. low operating temperatures. The details of the study are presented in the paper.

Greenhouse gas emissions (GHG) from light-duty vehicles have received attention recently because of increased focus on global warming and climate change. Relative to emissions of regulated pollutants like hydrocarbons and nitrogen oxides, nitrous oxide (N2O) emissions from all vehicles are generally very low. However, N2O is a powerful greenhouse gas, and small emissions of N2O can contribute substantially to total GHG inventories. Two fleets of different vehicle models, both meeting the current US Tier 1 emission standard, were evaluated in an effort to develop a better understanding of N2O emissions from modern three-way catalyst-equipped vehicles. Nine 1997 Ford Crown Victoria vehicles operating on clean-burning US Federal Phase 2 Reformulated Gasolines were assessed over 60,000 miles. For additional comparison, testing was also conducted with catalysts from six 1994 Toyota Camry vehicles, which had previously undergone 110,000 miles of controlled mileage accumulation.

Catalyzed gasoline particulate filters (cGPF) are one of the most effective emission control technologies for reducing gaseous and particulate emissions simultaneously. Successful adoption of this advanced technology relies on several important performance properties including low back pressure, high filtration efficiency and specially durability compliance. In this work using an underfloor cGPF, the backpressure control was achieved through optimizing catalyst coating technology and modifying the deposition profile of catalyst coating along GPF channels. Durability performance was demonstrated by using an accelerated engine aging method with selective blending of lubricating oils in fuel, which incorporates the aging mechanisms of thermal aging, ash loading, and soot accumulation/regeneration. The target durability demonstration represents 200,000 km real world operation.