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The National Renewable Energy Laboratory (NREL) collaborated with Millennium Cell and DaimlerChrysler to study heat and water management in a sodium borohydride (NaBH4) storage/processor used to supply hydrogen to a fuel cell in an automotive application. Knowledge of heat and water flows in this system is necessary to maximize the storage concentration of NaBH4, which increases vehicle range. This work helps evaluate the NaBH4 system's potential to meet the FreedomCAR program technical target of 6 wt% hydrogen for hydrogen storage technologies. This paper also illustrates the advantages of integrating the NaBH4 hydrogen processor with the fuel cell.

In cold climates batteries in electric and hybrid vehicles need to be preheated to achieve desired performance and life cycle of the energy storage system and the vehicle. Several approaches are available: internal core heating; external electric heating of a module; internal electric heating in the module around each cell, internal fluid heating around each cell; and external fluid heating around each module. To identify the most energy efficient approach, we built and analyzed several transient thermal finite element models of a typical battery. The thermal transient response of the battery core was computed for the first four heating techniques, which were compared based on the energy required to bring the battery to the desired temperature in a given time. Battery core heating was the most effective method to warm battery quickly with the least amount of energy. Heating the core by applying high frequency alternating currents through battery terminals is briefly discussed.

This research focuses on the technical issues that are critical to the adoption of high-energy-producing lithium Ion batteries. In addition to high energy density / high power density, this publication considers performance requirements that are necessary to assure lithium ion technology as the battery format of choice for electrified vehicles. Presentation of prime topics includes: • Long calendar life (greater than 10 years) • Sufficient cycle life • Reliable operation under hot and cold temperatures • Safe performance under extreme conditions • End-of-life recycling To achieve aggressive fuel economy standards, carmakers are developing technologies to reduce fuel consumption, including hybridization and electrification. Cost and affordability factors will be determined by these relevant technical issues which will provide for the successful implementation of lithium ion batteries for application in future generations of electrified vehicles.