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There are strong demands today to further improve the thermal efficiency of internal combustion engines against a backdrop of various environmental issues, including rising carbon dioxide (CO2) emissions and global warming. One factor that impedes efforts to improve the thermal efficiency of spark ignition engines is the occurrence of knocking. The aim of this study was to elucidate the details of knocking based on spectroscopic measurements and visualization of phenomena in the combustion chamber of a test engine that was operated on three primary reference fuels with different octane ratings (0 RON, 30 RON, and 50 RON). The ignition timing was retarded in the experiments to delay the progress of flame propagation, making it easier to capture the behavior of low-temperature oxidation reactions at the time knocking occurred.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted considerable interest in recent years as a new combustion concept for internal combustion engines. On the other hand, two combustion concepts proposed for two-cycle spark-ignition (SI) engines are Active Thermo-Atmosphere Combustion (ATAC) and Activated Radical (AR) combustion. The authors undertook this study to examine the similarities and differences between HCCI combustion and ATAC (AR) combustion. Differences in the low-temperature oxidation reaction behavior between these two combustion processes were made clear using one test engine.

Using absorption spectroscopy, simultaneous measurements were made of the behavior of the OH (characteristic spectrum of 306.4 nm), CH (431.5 nm) and C2(516.5 nm) radicals in the end-gas region and center of the combustion chamber of a spark-ignition engine during preflame reactions with four types of fuel having different octane numbers. The results of this research show that the behavior of the OH, CH and C2 radicals in preflame reactions differed significantly in both the center and end-gas region of the combustion chamber depending on the octane number of the fuel and also between normal and knocking combustion conditions.

Homogeneous Charge Compression Ignition (HCCI) engines have attracted much attention and are being widely researched as engines characterized by low emissions and high efficiency. However, one issue of HCCI engines is their limited operating range because of the occurrence of rapid combustion at high loads and misfiring at low loads. It is known that knocking accompanied by in-cylinder pressure oscillations also occurs in HCCI engines at high loads, similar to knocking seen in spark-ignition engines. In this study, HCCI combustion accompanied by in-cylinder pressure oscillations was visualized by taking high-speed photographs of the entire bore area. In addition, the influence of internal exhaust gas circulation (EGR) on HCCI knocking was also investigated. The visualized combustion images revealed that rapid autoignition occurred in the end-gas region during the latter half of the HCCI combustion process when accompanied by in-cylinder pressure oscillations.