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Technical Paper

A New Reduced Chemical Kinetic Model for Autoignition and Oxidation of Lean n-heptane/Air Mixtures in HCCI Engines

2005-04-11
2005-01-0118
The paper has presented a new reduced chemical kinetic model for the Homogeneous Charge Compression Ignition (HCCI) combustion of n-heptane in an engine, which contains 41 species and 63 reactions. The new model includes three sub-models: the first is the low-temperature reaction sub-model, which is established by determining particular aldehydes and small hydrocarbons in the model developed by Li et al. The second is the sub-model for large molecules decomposing directly into small molecules that is developed for linking the low-temperature reaction with high-temperature reaction. The third is used for high-temperature reaction, which is derived by several modifications to the model developed by Griffiths et al., eliminating several reactions, adding two oxidization reactions related to CO and CH3O.
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