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New combustion processes like LTC (Low Temperature Combustion) that includes HCCI (Homogeneous Charge Compression Ignition), PCCI (Premixed Charge Compression Ignition), PPCI (Partial Premixed Compression Ignition)… are promising ways to reduce simultaneously NOx and PM. Nevertheless, these combustion processes can be used only on a limited part of the engine load and speed map. Therefore, it appeared interesting to assess how the fuel, through its characteristics, could enhance the operating range in such combustion processes. That was the aim of an international consortium carried out by IFP and supported by numerous industrial companies. First a specific procedure has been developed to compare the different fuels on a early injection HCCI single cylinder engine. Then, using this procedure, a matrix of fuels having different cetane numbers (CN = 40-63), volatilities and chemical compositions has been tested.