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Air-to-fuel (A/F) ratio is the mass ratio of the air-to-fuel mixture trapped inside a cylinder before combustion begins, and it affects engine emissions, fuel economy, and other performances. Using an A/F ratio and dual-fuel ratio control oriented engine model, a multi-input-multi-output (MIMO) sliding mode control scheme is used to simultaneously control the mass flow rate of both port fuel injection (PFI) and direct injection (DI) systems. The control target is to regulate the A/F ratio at a desired level (e.g., at stoichiometric) and fuel ratio (ratio of PFI fueling vs. total fueling) to any desired level between zero and one. A MIMO sliding mode controller was designed with guaranteed stability to drive the system A/F and fuel ratios to the desired target under various air flow disturbances.