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Technical Paper

Catalyst Design for High Performance Engines Capable to Fulfill Future Legislation

2004-03-08
2004-01-1276
To meet future emission levels the industry is trying to reduce tailpipe emissions by both, engine measures and the development of novel aftertreatment concepts. The present study focuses on a joint development of aftertreatment concepts for gasoline engines that are optimized in terms of the exhaust system design, the catalyst technology and the system costs. The best performing system contains a close-coupled catalyst double brick arrangement using a new high thermal stable catalyst technology with low precious metal loading. This system also shows an increased tolerance against catalyst poisoning by engine oil.
Technical Paper

Aftertreatment Catalyst Design for the New DaimlerChrysler Supercharged 4-Cylinder Engine with Direct Gasoline Injection

2003-03-03
2003-01-1161
The launching of direct injection gasoline engines is currently one of the major challenges for the automotive industry in the European Union. Besides its potential for a notable reduction of fuel consumption, the engine with direct gasoline injection also offers increased power during stoichiometric and stratified operation. These advantages will most probably lead to a significant market potential of the direct injection concept in the near future. In order to meet the increasingly more stringent European emission levels (EURO IV), new strategies for the exhaust gas aftertreatment are required. The most promising technique developed in recent years, especially for NOx conversion in lean exhaust gases, is the so-called NOx storage catalyst.
Technical Paper

Deactivation of TWC as a Function of Oil Ash Accumulation - A Parameter Study

2005-04-11
2005-01-1097
The oil ash accumulation on modern three way catalyst (TWC) as well as its influence on catalyst deactivation is evaluated as a parameter of oil consumption, kind of oil additive compound and additive concentration. The oil ash accumulation is characterized by XRF and SEM/EDX in axial direction and into the washcoat depth of the catalyst. The deposition patterns of Ca, Mg, P and Zn are discussed. The catalytic activity of the vehicle and engine bench aged catalysts is measured by performing model gas tests and vehicle tests, respectively. The influence of oil ash accumulation on the lifetime emission behavior of the vehicle is discussed.
Technical Paper

Current Status and Prospects for Gasoline Engine Emission Control Technology - Paving the Way for Minimal Emissions

2000-03-06
2000-01-0856
The background for the development activities of the motor vehicle industry is strongly influenced by lawmakers, with engine development, in particular, coming under increasing pressure from the requirements of emissions legislation. Demands for CO2 reduction and thus corresponding savings in consumption contrast with regulations which call for compliance with extremely low emission levels, featuring the extreme of zero tailpipe emissions, and alternative low emission levels which make accurate measurement a problem even with current analysis technology. An example of such requirements are the SULEV limits of California law. These standards have given rise to a wide variety of emission control concepts, each of which, however, has certain limitations in its application. In the context of this general setting, the paper shows that the phase directly subsequent to cold start should be focused upon if these ambitious targets are to be reached.
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