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Selective Catalytic Reduction (SCR) diesel exhaust aftertreatment systems are virtually indispensable to meet NOx emissions limits worldwide. These systems generate the NH3 reductant by injecting aqueous urea solution (AUS-32/AdBlue®/DEF) into the exhaust for the SCR NOx reduction reactions. Understanding the AUS-32 injector spray performance is critical to proper optimization of the SCR system. Specifically, better knowledge is required of urea sprays under operating conditions including those where fluid temperatures exceed the atmospheric fluid boiling point. Results were previously presented from imaging of an AUS-32 injector spray which showed substantial structural differences in the spray between room temperature fluid conditions, and conditions where the fluid temperature approached and exceeded 104° C and “flash boiling” of the fluid was initiated.

In the present paper an innovative approach for the shot-to-shot hydraulic characterization of low pressure injection systems is experimentally assessed. The proposed methodology is an inverse application of the Zeuch’s method, which in this case is applied to a closed volume upstream the injector instead of downstream of it as in conventional injection analyzers. By this approach, the well-known constraint of having a finite volume pressurized with the injected liquid downstream the injector is circumvented. As a consequence, with the proposed instrument low pressure injectors - such as PFI, fed with gasoline or water, SCR injectors - can operate with the prescribed upstream-downstream pressure differential. Further, the injector can spray directly in atmosphere or in any ambient at arbitrary pressure and temperature conditions, allowing the simultaneous application of other diagnostics such as imaging, momentum flux measurement or sizing instruments.

The recent implementation of new rounds of stringent nitrogen oxides (NOx) emissions reduction legislation in Europe and North America is driving the expanded use of exhaust aftertreatment systems, including those that treat NOx under the high-oxygen conditions typical of lean-burn engines. One of the favored aftertreatment solutions is referred to as Selective Catalytic Reduction (SCR), which comprises a catalyst that facilitates the reactions of ammonia (NH3) with the exhaust nitrogen oxides (NOx). It is customary with these systems to generate the NH3 by injecting a liquid aqueous urea solution, typically at a 32% concentration of urea (CO(NH2)2). The solution is referred to as AUS-32, and is also known under its commercial name of AdBlue® in Europe, and DEF - Diesel Exhaust Fluid - in the USA. The urea solution is injected into the exhaust and transformed to NH3 by various mechanisms for the SCR reactions.

One of the favored automotive exhaust aftertreatment solutions used for nitrogen oxides (NOx) emissions reductions is referred to as Selective Catalytic Reduction (SCR), which comprises a catalyst that facilitates the reactions of ammonia (NH3) with the exhaust nitrogen oxides (NOx). It is customary with these systems to generate the NH3 by injecting a liquid aqueous urea solution (AUS-32) into the exhaust. The urea solution is injected into the exhaust and transformed to NH3 by various mechanisms for the SCR reactions. Understanding the spray performance of the AUS-32 injector is critical to proper optimization of the SCR injection system. Results were previously presented from imaging of an AUS-32 injector spray under hot exhaust conditions at the injector spray exit for an exhaust injection application.

A comprehensive experimental and numerical analysis of two state-of-the-art diesel AfterTreatment Systems (ATS) for automotive applications is presented in this work. Both systems, designed to fulfill Euro 6 emissions regulations standards, consist of a closed-coupled Diesel Oxidation Catalyst (DOC) followed by a Selective Catalytic Reduction (SCR) catalyst coated on a Diesel Particulate Filter (DPF), also known as SCR on Filter (SCRoF or SCRF). While the two systems feature the same Urea Water Solution (UWS) injector, major differences could be observed in the UWS mixing device, which is placed upstream of the SCRoF, whose design represents a crucial challenge due to the severe flow uniformity and compact packaging requirements.

Close-coupled aftertreatment systems (ATS) for automotive Diesel engines composed of DOC and SCR offer a significant potential in terms of pollutant emission control capability even with the introduction of more aggressive driving cycles and rigorous limits for type-approval tests. This is particularly important for incoming certification standards where the forecast is showing a trade-off towards ultra-low NOx emissions values. As the SCR system NOx conversion capability largely relies on both the UWS mixing device and on NOx sensors used to detect the actual NH3 slip and residual NOx concentration, developing numerical simulation tools for the analysis of the actual flow pattern and species concentration over peculiar sections of the exhaust system is crucial to support the ATS development process.