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Selective Catalytic Reduction (SCR) diesel exhaust aftertreatment systems are virtually indispensable to meet NOx emissions limits worldwide. These systems generate the NH3 reductant by injecting aqueous urea solution (AUS-32/AdBlue®/DEF) into the exhaust for the SCR NOx reduction reactions. Understanding the AUS-32 injector spray performance is critical to proper optimization of the SCR system. Specifically, better knowledge is required of urea sprays under operating conditions including those where fluid temperatures exceed the atmospheric fluid boiling point. Results were previously presented from imaging of an AUS-32 injector spray which showed substantial structural differences in the spray between room temperature fluid conditions, and conditions where the fluid temperature approached and exceeded 104° C and “flash boiling” of the fluid was initiated.

The recent implementation of new rounds of stringent nitrogen oxides (NOx) emissions reduction legislation in Europe and North America is driving the expanded use of exhaust aftertreatment systems, including those that treat NOx under the high-oxygen conditions typical of lean-burn engines. One of the favored aftertreatment solutions is referred to as Selective Catalytic Reduction (SCR), which comprises a catalyst that facilitates the reactions of ammonia (NH3) with the exhaust nitrogen oxides (NOx). It is customary with these systems to generate the NH3 by injecting a liquid aqueous urea solution, typically at a 32% concentration of urea (CO(NH2)2). The solution is referred to as AUS-32, and is also known under its commercial name of AdBlue® in Europe, and DEF - Diesel Exhaust Fluid - in the USA. The urea solution is injected into the exhaust and transformed to NH3 by various mechanisms for the SCR reactions.