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During transients, engines tend to produce substantially higher peak emissions like soot - the main fraction of particular matter (PM) - which are the longer the more important as the steady state emissions are better controlled. While Diesel particulate filters are normally able to block them, preventing their occurrence would of course be more important. In order to achieve this goal, however, they must be measurable. While for most emissions commercial sensors of sufficient speed and performance are available, the same is not true for PMs, especially for production engines. Against this background, in the last years the possible use of a full stream 50Hz sensor based on Laser Induced Incandescence (LII) was investigated, and the results were very encouraging, showing that the sensor could recognize transient changes undetected by conventional measurement systems (like the AVL Opacimeter) but confirmed by the analysis of combustion.

In a typical diesel engine exhaust aftertreatment system consisting of a diesel oxidation catalyst (DOC), a diesel particulate filter (DPF) and a selective catalytic reduction (SCR) system the main purpose of the DOC, besides the oxidation of CO to CO₂, is the oxidation of NO to NO₂. The NO to NO₂ conversion is an essential contribution for the downstream SCR system because the fast SCR reaction which provides the highest conversion rates of NOx to H₂O and N₂ works well only under roughly equal concentrations of NO and NO₂. The typical amount of NO to NOx ratio produced by the engine is about 0.95, hence the DOC is necessary to decrease this coefficient close to 0.50. Due to the temperature dependency of the DOC reaction mechanism the oxidation of NO to NO₂ takes only place sufficiently if the temperature of the DOC is higher than 200°C, which, however, cannot be reached during low engine speed and low load situations.

The emissions of modern Diesel engines, which are known to have various health effects, are beside the drivers torque demands and low fuel consumptions one of the most challenging issues for combustion and after treatment control. To comply with legal requirements, emission control for heavy duty engines is not feasible without additional hardware, usually consisting of a Diesel oxidation catalyst (DOC), a Diesel particulate filter (DPF) and a selective catalytic reduction (SCR) system. In contrast to other NOx reduction systems, e.g. lean NOx traps, the SCR system requires an additional ingredient, namely ammonia (NH3), to reduce the NOx emissions to non harmful components. Consequently, the correct amount of NH3 dosing in the SCR catalyst is one of the critical components to reach high conversion rates and avoid ammonia slip.

The focus in the development of modern exhaust after treatment systems, like the Diesel Oxidation Catalyst (DOC), the Diesel Particulate Filter (DPF) and Selective Catalytic Reduction (SCR), is to increase on one hand the oxidation rates of Carbon monoxide (CO), HC (Hydro Carbons) and NO (Nitrogen Oxide) and on the other hand the reduction rates of Particulate Matter (PM) and the NOx emissions to fulfill the more and more restricting requirements of the exhaust emission legislation. The simplest, practical most relevant way to obtain such a dosing strategy of a SCR system is the use of a nonlinear map, which has to be determined by extensive calibration efforts. This feedforward action has the advantage of not requiring a downstream NOx sensor and can achieve high conversion efficiency under steady-state operating conditions for nominal systems.