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This paper describes a model for the simulation of the joint operation of internal combustion engine (ICE) with methanol reformer when the ICE is fed by the methanol steam reforming (SRM) products and the energy of the exhaust gases is utilized to sustain endothermic SRM reactions. This approach enables ICE feeding by a gaseous fuel with very favorable properties, thus leading to increase in the overall energy efficiency of the vehicle and emissions reduction. Previous modeling attempts were focused either on the performance of ICE fueled with SRM products or on the reforming process simulation and reactor design. It is clear that the engine performance is affected by the composition of the reforming products and the reforming products are affected by the exhaust gas temperature, composition and flow rate.

A computer model was built and a theoretical analysis was performed to predict the behavior of a system containing Homogenous charge compression ignition (HCCI) engine and a methanol reformer. The reformer utilizes the waste heat of the exhaust gases to sustain the two subsequent processes: dehydration of methanol to dimethyl ether (DME) and water, and methanol steam reforming (SRM) where methanol and water react to mainly hydrogen, CO and CO2. Eventually, a gaseous mixture of DME, H2, CO, CO2, water (reused) and some other species is created in these processes. This mixture is used for the engine feeding. By adding water to the methanol and fixing the vaporized fuel's temperature, it is possible to manage the kinetics of chemical processes, and thus to control the products’ composition. This allows controlling the HCCI combustion.

The goal of the present work was to analyze the performance of a spark ignition engine fueled by ethanol steam reforming products. The highest reformer-ICE system efficiency and the lowest CO emissions were achieved with the ethanol steam reforming products obtained at reaction temperature of 1000K and water/ethanol ratio of 1.8. Fueling the SI engine with reformate gas made it possible to achieve the reformer-ICE system efficiency of 40% for the engine fed by SRE products compared with 34% for gasoline and 36% for ethanol. CO emissions were reduced by 3.5 and 10 times compared with ethanol and gasoline, respectively. NO emissions were decreased by about 4 times compared with the gasoline-fed engine.

A comparative theoretical analysis of the spark ignition (SI) engine performance is performed for the cases of feeding it by the reforming products of two different alcohols: ethanol and methanol. Energy efficiency of the steam reforming process, optimal reactor temperature and obtainable compositions of the reforming products are showed and analyzed for the considered two fuel types. Three compositions of the reforming products: ethanol steam reforming (SRE), methanol steam reforming (SRM) and products of the low-temperature ethanol reforming are considered as gaseous fuels in the engine performance simulations. Change in the fuel burning velocity as a function of fuel composition and air excess factor is taken into account in a modeling of the heat release process.

In this paper we describe conversion of the gen-set gasoline-fed carburetor single-cylinder SI engine to the direct-injection version operating with the gaseous hydrogen-rich methanol reforming products, and present the first experimental results. It was found that engine feeding by methanol steam reforming products has a great potential of pollutant emissions mitigation as compared with gasoline. NOx concentrations in the exhaust gas were reduced by a factor of 7 as a result of the lean combustion and lowering in-cylinder temperatures. Particle mass emissions were mitigated to zero-impact levels. Harmful emissions of the target pollutants THC, CO and the GHG gas CO2 were reduced by a factor of 6, 25 and 1.5, respectively.