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GDI injection systems have become dominant in passenger cars due to their flexibility in managing and advantages in the fuel economy. With the increasingly stringent emissions regulations and concurrent requirements for enhanced engine thermal efficiency, a comprehensive characterization of the fuel spray behavior has become essential. Different engine loads produce in a variety of fuel supplying conditions that affect the air/fuel mixture preparation and influence the efficiency and pollutant production. The flash boiling is a particular state that occurs for peculiar thermodynamic conditions of the engine. It could strongly influence the mixture in sub-atmospheric environments with detrimental effects on emissions. In order to obtain an in-depth understanding of the flash boiling phenomena, it is necessary to study the parameters influencing the mixture formation and their appearance in diverse engine conditions.