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E-fuels are proven to be a major contributing factor to reduce CO2 emissions in internal combustion engines. In gasoline engines, C1 oxygenate are seen as critical to reach CO2 and emission reduction goals. Their properties affect the fuel injection characteristics and thus the fuel mixture formation and combustion emissions. To exploit the full potential of e-fuels, the detailed knowledge of their spray characteristic is necessary. The correlation between the fuel content of C1 oxygenates and particulate emissions do not appear to be linear. To understand this correlation, the spray characteristics have to be investigated in detail. The reduced stoichiometric air requirement leads to an increase of the injected fuel mass, which has to evaporate. This can lead to a changed fuel film interaction within the combustion chamber walls and therefore a change of particle formation.