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Over the past few years, the growing concerns about global warming and efforts to reduce engine-out emissions have made the dual-fuel (DF) engines more popular in marine and power industries. The use of natural gas as an alternative fuel in DF engines has both the environmental and economic advantages over the conventional diesel combustion. However, the misfire phenomenon at lean conditions limits the operating range of DF combustion and causes emissions of unburned hydrocarbon (UHC) and unburned methane (methane-slip) in the environment. The greenhouse effect of methane is considered 28 times greater than CO2 over a 100-year perspective, which raises concerns for the governments and marine engine manufacturers. In efforts to reduce the UHC and methane-slip from DF engines, this study discusses ethane enrichment of diesel-methane DF combustion in a full-metal single-cylinder research engine under lean condition (λGFB = ~2.0) while keeping the total-fuel energy rather constant.