Search Results

An unified model with a single set of kinetic parameters has been proposed for modeling laminar flame velocities of several alkanes using detailed kinetic mechanisms automatically generated by the EXGAS software. The validations were based on recent data of the literature. The studied compounds are methane, ethane, propane, n-butane, n-pentane, n-heptane, iso-octane, and two mixtures for natural gas and surrogate gasoline fuel. Investigated conditions are the following: unburned gases temperature was varied from 300 to 600 K, pressures from 0.5 to 25 bar, and equivalence ratios range from 0.4 to 2. For the overall studied compounds, the agreement between measured and predicted laminar burning velocities is quite good.

The influence of the addition of oxygenated hydrocarbons to diesel fuels has been studied, using a detailed chemical kinetic model. Resulting changes in ignition and soot precursor production have been examined. N-heptane was used as a representative diesel fuel, and methanol, ethanol, dimethyl ether, dimethoxymethane and methyl butanoate were used as oxygenated fuel additives. It was found that addition of oxygenated hydrocarbons reduced the production of soot precursors. When the overall oxygen content in the fuel reached approximately 30-40 % by mass, production of soot precursors fell effectively to zero, in agreement with experimental studies. The kinetic factors responsible for these observations are discussed.