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In this work, a 5-zone model has been applied to replicate the in-cylinder conditions evolution of a Rapid Compression-Expansion Machine (RCEM) in order to improve the chemical kinetic analyses by obtaining more accurate simulation results. To do so, CFD simulations under motoring conditions have been performed in order to identify the proper number of zones and their relative volume, walls surface and temperature. Furthermore, experiments have been carried out in an RCEM with different Primary Reference Fuels (PRF) blends under homogeneous conditions to obtain a database of ignition delays and in-cylinder pressure and temperature evolution profiles. Such experiments have been replicated in CHEMKIN by imposing the heat losses and volume profiles of the experimental facility using a 0-D 1-zone model. Then, the 5-zone model has been analogously solved and both results have been compared to the experimental ones.

Soot radiation has an important contribution to the overall heat losses in a combustion chamber of a DI diesel engine. The aim of this study was to develop a soot radiation model coupled to a soot formation/oxidation sub-model, which is also described in the paper. On the one hand, the soot radiation model is based on the available knowledge of the radiation of a soot cloud commonly used to apply the two-color method to diesel sprays. On the other hand, it was tuned and validated with experimental data: the optical thickness, KL, obtained from the laser extinction method, and the radiation intensity at two different wavelengths. Once the model was validated, the overall radiated power was calculated taking into account the radiation absorption caused by the spray itself. This power was compared to the one released by the spray combustion process, and the results were in agreement with other studies available in the literature.