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The small engine for two-wheel vehicles has generally high possibility to be optimized at low speeds and high loads. In these conditions fuel consumption and pollutants emission should be reduced maintaining the performance levels. This optimization can be realized only improving the basic knowledge of the thermo-fluid dynamic phenomena occurring during the combustion process. It is known that, during the fuel injection phase in PFI SI engines, thin films of liquid fuel can form on the valves surface and on the cylinder walls. Successively the fuel films interact with the intake manifold and the combustion chamber gas flow. During the normal combustion process, it is possible to achieve gas temperature and mixture strength conditions that lead to fuel film ignition. This phenomenon can create diffusion-controlled flames that can persist well after the normal combustion event. These flames induce the emission of soot and unburned hydrocarbons.

The role of Spark Ignition (SI) and Diesel engines as nanoparticles sources in urban area was investigated. Detection, sizing and counting of particles were realized at the exhaust of a Port Fuel Injection Spark Ignition (PFI SI) engine equipped with a Three-Way Catalyst (TWC) and a Unijet Common Rail (CR) Diesel engine equipped first with an Oxidation Catalyst (OC) and then with a Catalyzed Diesel Particulate Filter (CDPF). Engine operating conditions in high road traffic were considered. Electrical Low Pressure Impactor (ELPI) was used as real-time measurements device for particle size distribution in the range from 7 nm up to 10000 nm. Broadband UV-Visible Extinction and Scattering Spectroscopy (BUVESS) allowed investigating the chemical and physical nature of emitted particles. It was observed that the major contribution to particulate mass is due to Diesel engine equipped with the OC, the other engines contribute only in terms of number concentration.