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Technical Paper

A Study of Emission Durability and Ash Accumulation of “Advanced Three-way Catalyst Integrated on Gasoline Particulate Filter” for BS6 (Stage2) Applications

2021-09-22
2021-26-0182
India BS6 Stage2 (2023) regulations demand all gasoline direct injection (GDI) vehicles to meet particulate number emissions (PN) below 6x10+11# per km. Gasoline particulate filters (GPF) are a proven technology and enable high PN filtration efficiencies throughout the entire vehicle lifetime. One challenge for GPF applications could be the changing emission performance characteristics as a function of mileage due to collected ash and/or soot deposits with implications on back pressure losses. The main objective of this technical contribution is to study the above-mentioned challenges while applying Indian driving conditions and typical Indian climate and other ambient conditions. The substrate technology selected for this study is a high porosity GPF designed to enable the integration of a three-way functionality into the GPF, commonly described as catalyzed GPF (cGPF).
Journal Article

Application of Catalyzed Gasoline Particulate Filters to GDI Vehicles

2012-04-16
2012-01-1244
With the introduction of limits for particle numbers besides particle mass emitted by light duty vehicles new pollution control devices like catalyzed gasoline particulate filters (GPF) might be required. GPFs need to address the challenge to provide sufficient particle number reduction at acceptable pressure drop in addition while having high conversion efficiencies for regulated pollutants. The emission performance of gasoline particulate filters coated with a three-way functional washcoat was examined. The impact of the washcoat on particle filtration efficiency was investigated, as well as its impact on the conversion efficiencies for hydrocarbons, carbon monoxide and nitrous oxides. Moreover, it was found that the precious metal containing washcoat accelerates the regeneration of a filter when loaded with artificial soot.
Technical Paper

Effect of Engine-Out Soot Emissions and the Frequency of Regeneration on Gasoline Particulate Filter Efficiency

2020-04-14
2020-01-1431
Gasoline particulate filters (GPFs) are an important aftertreatment system that enables gasoline direct injection (GDI) engines to meet current emission standardsn note of GPFs may need to improonont accumulates on the GPF during engine operation. GPFs are often ‘pa during vehicle operation when the exhaust is sufficiently hot and it contains sufficient oxygen. This paper explores the effect that engine-out soot emissions and the frequency of GPF regeneration have on GPF filtration efficiency. Two GPF technologies were tested on two engine dynamometers as well as two production vehicles on a chassis dynamometer. The engines span a wide range of engine-out particle emissions (a range of almost one order of magnitude). The filtration efficiency of the GPFs were measured with a regulation-compliant particle number system (non-volatile particles > 23 nm), as well as with a particle counter with a lower cutoff of 2.5 nm, and with a differential mobility spectrometer.
Technical Paper

Impact of European Real-Driving-Emissions Legislation on Exhaust Gas Aftertreatment Systems of Turbocharged Direct Injected Gasoline Vehicles

2017-03-28
2017-01-0924
Recently, the European Union has adopted a new regulation on Real-Driving-Emissions (RDE) and also China is considering RDE implementation into new China 6 legislation. The new RDE regulation is focused on measuring nitrogen oxides (NOx) and particulate number (PN) emissions of both light-duty gasoline and diesel vehicles under real world conditions. A supplemental RDE test procedure was developed for European type approval, which includes on-road testing with cars equipped with portable emission measurement systems (PEMS). This new regulation will significantly affect the engine calibrations and the exhaust gas aftertreatment. In this study the impact of the new RDE regulation on two recent EU 6b certified turbocharged direct injected gasoline vehicles has been investigated. A comparison of several chassis dyno drive cycles with two new defined on-road RDE cycles was performed.
Technical Paper

Comprehensive Gasoline Exhaust Gas Aftertreatment, an Effective Measure to Minimize the Contribution of Modern Direct Injection Engines to Fine Dust and Soot Emissions?

2014-04-01
2014-01-1513
With the growing awareness about the presence of fine/ultra fine particulates in the ambient air and their negative impact on climate and health, some regions of the world have started to look closer at the contribution of road traffic. Since Gasoline engines, in particular when injecting fuel directly into the combustion chamber, proved to emit relevant numbers of particulates, even hardly visible, the growing share of Gasoline DI engines and their small size of particulate emissions is a concern. To address the same, the EU has already set limits for the particulate number with EU6 from 2015 onwards. The US considers setting challenging limits by particulate mass. Since mass of ultra fine particulates is very low and difficult to measure, experts investigate if a measurement by number might better address the particular concern. The implementation of a coated Particulate Filter enables meeting not only basic demands during traditional emission test cycles.
Technical Paper

Secondary Emission Control towards Post China 6 Legislation

2021-04-06
2021-01-0580
China 6 emission legislation was finalized in 2018 and the full implementation nationwide is postponed to 2021 due to COVID-19. It is foreseen that the post China 6 legislation will have more stringent primary and secondary emission requirements including further reduction of nitrous oxide (N2O) emissions and likely to include limits on ammonia (NH3) emissions. This study investigated the secondary emissions (i.e. N2O and NH3) of a variety of China 6 production gasoline vehicles operating under the worldwide harmonized light vehicles test cycle (WLTC) and random test standardized aggressive (RTS 95) cycle. It was found that N2O emissions were less than 5 mg/km on all these vehicles, far below the current China 6 limit (20 mg/km), however NH3 emissions varied from 2 to 48 mg/km among the production vehicles. The mechanisms of N2O and NH3 formation and their correlation with primary emissions were also investigated.
Technical Paper

Experimental Study on the Impact of Lubricant Ash on CN6 After-Treatment System Performance of GDI Vehicle

2021-04-06
2021-01-0586
In order to study the influence of lubricant ash on the performance of the CN6 after-treatment system, especially the catalyst characteristics of Coated Gasoline Particulate Filter (CGPF), the system was rapidly aged on the engine bench by blending combustion method, and the ash content of 60g represented the endurance of 200kkm CGPF. The effects of CGPF with different endurance mileage on particulate matter emission, gas light-off temperature and engine performance of a Gasoline Direct Injection (GDI) vehicle were studied on the engine bench, chassis dynamometer and real-road tests. Finally, the ash distribution was analyzed by computed tomography (CT). The results showed that the vehicle equipped with CGPF could meet the requirements of CN6 particulate and gas emission limits under both worldwide harmonized light vehicles test cycle (WLTC) and real driving emission (RDE) tests.
Technical Paper

Advanced TWC Technology to Cover Future Emission Legislations

2015-04-14
2015-01-0999
The new emission regulations in Europe, EU 6 will promulgate more realistic driving conditions with more stringent HC, CO, NOx and particulate emissions. This legislation will also include the WLTP (Worldwide harmonized Light vehicles Test Procedure) cycle for CO2 measurements and a new requirement called “Real-Driving-Emissions” (RDE) as well. The RDE requirement is to ensure modern vehicles comply with the legislation under all conditions of normal driving. More robust aftertreatment solutions are needed to meet these new requirements. This work introduces an improved three-way catalyst (TWC) for gasoline engines for these new regulations. It is tested under static and dynamic conditions and on several engines and vehicles with various drive cycles. It offers better thermal stability combined with lower backpressure than former TWC generations.
Journal Article

Catalysts for Post Euro 6 Plug-In Hybrid Electric Vehicles

2020-04-14
2020-01-0354
Due to benefits from the use of electric power, Hybrid Electric Vehicles (HEVs) and Plug-in Hybrid Electric Vehicles (PHEVs) are regarded to be superior over conventional Internal Combustion Engine (ICE) only vehicles in fuel economy and emissions. However, recent studies find out that this is not always true. On certain conditions, hybrid vehicles can be even more polluted. In order to identify these challenges and develop catalysts to meet more stringent emission requirement in the future, e.g. Euro 7, for hybrid application, as a part of our xHEV project, this study includes exclusively extensive investigation on a latest Euro 6d temp Parallel PHEV.
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