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Gasoline Direct Injection Compression Ignition (GDCI) is a partially premixed low temperature combustion process that has demonstrated high fuel efficiency with full engine load range capabilities, while emitting very low levels of particulate matter (PM) and oxides of nitrogen (NOx). In the current work, a comparison of engine combustion, performance, and emissions has been made among E10 gasoline and several full-boiling range naphtha fuels on a Gen 2 single-cylinder GDCI engine with compression ratio of 15:1. Initial results with naphtha demonstrated improved combustion and efficiency at low loads. With naphtha fuel, hydrocarbon and carbon monoxide emissions were generally reduced at low loads but tended to be higher at mid-loads despite the increased fuel reactivity. At higher loads, naphtha required less boost pressure compared to gasoline, however, up to 20% additional EGR was required to maintain combustion phasing.