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The emissions from a direct injection diesel engine measured according to the ECE R49 13-mode cycle and as a function of exhaust gas recirculation are compared for diesel fuel without water addition, and for water-in-diesel as emulsion and microemulsion. The effect of water addition on the soot emissions was remarkably strong for both the emulsion and microemulsion fuels. The average weighted soot emission values for the 13-mode cycle were 0.0024 and 0.0023 g/kWh for the two most interesting emulsion and microemulsion fuels tested, respectively; 5-fold lower than the US 2007 emission limit.

Having low aromatic compounds, high cetane rating, higher heat of combustion and almost zero sulphur content, a new paraffinic fuel (NPF), developed by Oroboros AB Sweden, was believed to receive attention as a new alternative fuel. Therefore, further investigation and combustion analyses were conducted in a research single-cylinder diesel engine, where detailed thermodynamic analyses were performed by Burst to File high frequency signal sampling code and by the Dragon software, revealing the real thermochemistry history. The aim of this investigation was an effort to reduce the pollution levels in Santiago de Chile by introducing this new paraffinic fuel (NPF). Experimental results have shown that the NPF fuel has a significant impact not only on the emission levels, but also on other energetic parameters of the engine such as ignition delay, cylinder peak pressure, heat release gradient, indicated efficiency etc.