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Hydrogen crossover and membrane hydration are significant issues for polymer electrolyte fuel cells (PEFC). Hydrogen crossover amounts to a quantity of unspent fuel, thereby reducing the fuel efficiency of the cell, but more significantly it also gives rise to the formation of hydrogen peroxide in the cathode catalyst layer which acts to irreversibly degenerate the polymer electrolyte. Membrane hydration not only strongly governs the performance of the cell, most noticeable through its effect on the ionic conductivity of the membrane, it also influences the onset and propagation of internal degradation and failure mechanisms that curtail the reliability and safety of PEFCs. This paper focuses on how hydrogen crossover and membrane hydration are affected by; (a) characteristic cell geometries, and (b) operating conditions relevant to automotive fuel cells.

Extensive research has been performed for on-board hydrogen generation, such as pyrolysis of metal hydrides (e.g., LiH, MgH₂), hydrogen storages in adsorption materials (e.g., carbon nanotubes and graphites), compressed hydrogen tanks and the hydrolysis of chemical hydrides. Among these methods, the hydrolysis of NaBH₄ has attracted great attention due to the high stability of its alkaline solution and the relatively high energy density, with further advantages such as moderate temperature range (from -5°C to 100°C) requirement, non-flammable, no side reactions or other volatile products, high purity H₂ output. The H₂ energy density contained by the system is fully depend on the solubility of the complicated solution contains reactant, product and the solution stabilizer. In this work, an approach based on thermodynamic equilibrium was proposed to model the relationship between the solubility of an electrolyte and temperature, and the effect of another component on its solubility.