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This work presents an application of two sub-models relative to chemical-kinetics-based turbulent pre-mixed combustion modeling approach on the simulation of burn rate and emissions of spark ignition engines. In present paper, the justification of turbulent pre-mixed combustion modeling directly based on chemical kinetics plus a turbulence model is given briefly. Two sub-models relative to this kind of pre-mixed combustion modeling approach are described generally, including a practical PRF (primary reference fuel) chemical kinetic mechanism which can correctly capture the laminar flame speed under a wide range of Ford SI (spark ignition) engines/operating conditions, and an advanced spark plug ignition model which has been developed by Ford recently.

In the present work, five surrogate components (n-Hexadecane, n-Tetradecane, Heptamethylnonane, Decalin, 1-Methylnaphthalene) are proposed to represent liquid phase of diesel fuel, and another different five surrogate components (n-Decane, n-Heptane, iso-Octane, MCH (methylcyclohexane), Toluene) are proposed to represent vapor phase of diesel fuel. For the vapor phase, a 5-component surrogate chemical kinetic mechanism has been developed and validated. In the mechanism, a recently updated H2/O2/CO/C1 detailed sub-mechanism is adopted for accurately predicting the laminar flame speeds over a wide range of operating conditions, also a recently updated C2-C3 detailed sub-mechanism is used due to its potential benefit on accurate flame propagation simulation. For each of the five diesel vapor surrogate components, a skeletal sub-mechanism, which determines the simulation of ignition delay times, is constructed for species C4-Cn.