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During recent years, the deterioration of greenhouse phenomenon, in conjunction with the continuous increase of worldwide fleet of vehicles and crude oil prices, raised heightened concerns over both the improvement of vehicle mileage and the reduction of pollutant emissions. Diesel engines have the highest fuel economy and thus, highest CO2 reduction potential among all other thermal propulsion engines due to their superior thermal efficiency. However, particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines are comparatively higher than those emitted from modern gasoline engines. Therefore, reduction of diesel emitted pollutants and especially, PM and NOx without increase of specific fuel consumption or let alone improvement of diesel fuel economy is a difficult problem, which requires immediate and drastic actions to be taken.

Despite the improvement in HD Diesel engine out emissions future emission legislation requires significant reduction of both NOx and particulate matter. To accomplish this task various solutions exist involving both internal and external measures. As widely recognized, it will be possibly required to employ both types of measures to meet future emission limits. Towards this direction, it is necessary to reduce NOx further using internal measures. Several solutions exist in that area, but the most feasible ones according to the present status of technical knowledge are EGR, water injection or fuel/water emulsions. These technologies aim to the reduction of both the gas temperature and oxygen concentration inside the combustion chamber that strongly affect NOx formation. However, there remain open points mainly concerning the effectiveness of water addition techniques and penalties related to bsfc and soot emissions.

Considering future emission legislation for HD diesel engines it is apparent that it will be probably necessary to employ A/T devices to achieve them. The main problem concerns the simultaneous control of both NOx and particulate emissions at an acceptable fuel penalty. Concerning particulate matter the use of particulate traps is considered to be a proven technology while for NOx emission control; various solutions exist mainly being the use of SCR catalysts or LNT devices. But LNT traps require periodical regeneration, which is accomplished by generating reducing agents i.e. CO and H2. The present investigation focuses on the regeneration of LNT devices through the engine operating cycle. This can be achieved using two techniques, additional injection of fuel at the exhaust manifold (external measures) or operation at low lambda values in the range of 1.0 or lower (internal measures).

A major challenge for researchers and engineers in the field of diesel engine development is the simultaneous reduction of both NOx and soot emissions from diesel engines to comply with strict future emission legislation. One of the promising internal measures that focus on the reduction of soot emissions is post fuel injection which does not have a serious effect on NOx emissions. The main parameters involved when using this technique are post fuel quantity and dwell angle between the main and the post fuel injection events. In the present work a detailed computational investigation has been conducted to determine the effect of post fuel injection on engine performance and pollutant emissions (NOx and soot). To this scope, a phenomenological multi-zone combustion model has been used, properly modified to take into account the interaction of post and main injected fuel amounts.

The past decade significant research effort has concentrated on the DI diesel engine due to stringent future emission legislation which requires drastic reduction of engine tail pipe pollutant emissions, mainly PM and NOx, without significant deterioration of specific fuel consumption. Towards this effort, the important role of modeling to investigate and understand the impact of various internal measures on combustion and emissions has been widely recognized. Phenomenological models can significantly contribute towards this direction because they have acceptable prediction capability and the advantage of low computational time. This enables the production of results, on a cycle basis, that indicate the effect of various parameters on both engine performance and emissions. Therefore their use can significantly reduce engine development time (i.e. reduction of experimental effort) and cost.

Homogeneous Charge Compression Ignition (HCCI) engines have the potential of reducing NOx emissions as compared to conventional Diesel or SI engines. Soot emissions are also very low due to the premixed nature of combustion. However, the unburned hydrocarbon emissions are relatively high and the same holds for CO emissions. The formation of these pollutants, for a given fuel, is strongly affected by the temperature distribution as well as by the charge motion within the engine cylinder. The foregoing physical mechanisms determine the local ignition timing and burning rate of the charge affecting engine efficiency, performance and stability. Obviously the success of any model describing HCCI combustion depends on its ability to describe adequately both the chemistry of combustion and the physical phenomena, i.e. heat and mass transfer within the cylinder charge. In the present study a multi-zone model is developed to describe the heat and mass transfer mechanism within the cylinder.

The compression ignition engine of the dual fuel type has been employed in a wide range of applications to utilize various gaseous fuel resources while minimizing soot and oxides of nitrogen emissions without excessive increase in cost from that of conventional direct injection diesel engines. The use of natural gas as a supplement for liquid diesel fuel could be a solution towards the efforts of an economical and clean burning operation. The high auto-ignition temperature of natural gas is a serious advantage since the compression ratio of most conventional diesel engines can be maintained. In the present work a comparison between experimental and theoretical results is presented under dual fuel operation. For the theoretical investigation a computer simulation model has been developed which simulates the gaseous fuel combustion processes in dual fuel engines.

During the last years a great effort has been made by many NATO nations to move towards the use of one military fuel for all the land-based military aircraft, vehicles and equipment employed on the military arena. This idea is known to as the Single Fuel Concept (SFC). The fuel selected for the idea of SFC is the JP-8 (F-34) military aviation fuel which is based upon the civil jet fuel F-35 (Jet A-1) with the inclusion of military additives possessing anti-icing and lubricating properties. An extended experimental investigation has been conducted in the laboratory of Thermodynamic and Propulsion Systems at the Hellenic Air Force Academy. This investigation was conducted with the collaboration of the respective laboratories of National Technical University of Athens and Hellenic Naval Academy as well.

Worldwide demand for reduction of automotive fuel consumption and carbon dioxide emissions results in the introduction of new diesel engine technologies. A promising technique for increasing the power density of reciprocating engines, improving fuel economy and curtailing engine exhaust emissions is the use of variable compression ratio (VCR) technology. Several automotive manufacturers have developed prototype vehicles equipped with VCR gasoline engines. The constructive pattern followed to alter the compression ratio varies with the manufacturer. The implementation of VCR technology offers two main advantages: the reduction of CO2 emissions due to optimal combustion efficiency in the entire range of engine operating conditions and the increase of power concentration due to high boosting of a small engine displacement (i.e., engine downsizing).

Diesel engine manufacturers are currently intensifying their efforts to meet future emission limits that require a drastic reduction of NOx and particulate matter compared to present values. Even though several after-treatment techniques have been developed for tailpipe NOx reduction in heavy duty diesel engines, the in-cylinder control of NOx formation still remains of utmost importance. Various methods have been used to control NOx formation in diesel engines such as retarded injection timing and EGR providing each one of them very promising results. However, use of these techniques is accompanied by penalties in specific fuel consumption and exhaust soot. A promising technology for NOx reduction especially for heavy-duty diesel engines and mainly large scale ones is the addition of water to the combustion chamber to reduce peak combustion temperature that obviously affects NOx formation.

During the past years most fundamental research worldwide has been concentrated on the direct injection diesel engine (DI). This engine has a lower specific fuel consumption when compared to the indirect injection diesel engine (IDI) used up to now in most passenger cars. But the application of the direct injection engine on passenger cars and light trucks has various problems. These are associated mainly with its ability to operate at high engine speeds due to the very low time available for combustion. To overcome these problems engineers have introduced various techniques such as swirl and squish for the working fluid and the use of extremely high pressure fuel injection systems to promote the air-fuel mixing mechanism. The last requires the solution of various problems associated with the use of the high pressure and relatively small injector holes.