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Journal Article

Development of an Ammonia Reduction Aftertreatment Systems for Stoichiometric Natural Gas Engines

2017-01-10
2017-26-0143
Three-way catalyst equipped stoichiometric natural gas vehicles have proven to be an effective alternative fuel strategy that has shown superior low NOx benefits in comparison to diesels equipped with SCR. However, recent studies have shown the TWC activity to contribute to high levels of tailpipe ammonia emissions. Although a non-regulated pollutant, ammonia is a potent pre-cursor to ambient secondary PM formation. Ammonia (NH3) is an inevitable catalytic byproduct of TWCduring that results also corresponds to lowest NOx emissions. The main objective of the study is to develop a passive SCR based NH3 reduction strategy that results in an overall reduction of NH3 as well as NOx emissions from a stoichiometric spark ignited natural gas engine. The study investigated the characteristics of Fe-based and Cu-based zeolite SCR catalysts in storage, and desorption of ammonia at high exhaust temperature conditions, that are typical of stoichiometric natural gas engines.
Journal Article

Summary of In-use NOx Emissions from Heavy-Duty Diesel Engines

2008-04-14
2008-01-1298
As part of the 1998 Consent Decrees concerning alternative ignition strategies between the six settling heavy-duty diesel engine manufacturers and the United States government, the engine manufacturers agreed to perform in-use emissions measurements of their engines. As part of the Consent Decrees, pre- (Phase III, pre-2000 engines) and post- (Phase IV, 2001 to 2003 engines) Consent Decree engines used in over-the-road vehicles were tested to examine the emissions of oxides of nitrogen (NOx) and carbon dioxide (CO2). A summary of the emissions of NOx and CO2 and fuel consumption from the Phase III and Phase IV engines are presented for 30 second “Not-to-Exceed” (NTE) window brake-specific values. There were approximately 700 Phase III tests and 850 Phase IV tests evaluated in this study, incorporating over 170 different heavy duty diesel engines spanning 1994 to 2003 model years. Test vehicles were operated over city, suburban, and highway routes.
Technical Paper

Parametric Study of 2007 Standard Heavy-Duty Diesel Engine Particulate Matter Sampling System

2007-01-23
2007-01-0060
Heavy-Duty Diesel (HDD) engines' particulate matter (PM) emissions are most often measured quantitatively by weighing filters that collect diluted exhaust samples pre- and post-test. PM sampling systems that dilute exhaust gas and collect PM samples have different effects on measured PM data. Those effects usually contribute to inter-laboratory variance. The U.S. Environmental Protection Agency (EPA)'s 2007 PM emission measurement regulations for the test of HDD engines should reduce variability, but must also cope with PM mass that is an order of magnitude lower than legacy engine testing. To support the design of a 2007 US standard HDD PM emission sampling system, a parametric study based on a systematic Simulink® model was performed. This model acted as an auxiliary design tool when setting up a new 2007 HDD PM emission sampling system in a heavy-duty test cell at West Virginia University (WVU). It was also designed to provide assistance in post-test data processing.
Technical Paper

Nano Particulate Matter Evolution in a CFR1065 Dilution Tunnel

2009-11-02
2009-01-2672
Dual primary full-flow dilution tunnels represent an integral part of a heavy-duty transportable emissions measurement laboratory designed and constructed to comply with US Code of Federal Regulations (CFR) 40 Part 1065 requirements. Few data exist to characterize the evolution of particulate matter (PM) in full scale dilution tunnels, particularly at very low PM mass levels. Size distributions of ultra-fine particles in diesel exhaust from a naturally aspirated, 2.4 liter, 40 kW ISUZU C240 diesel engine equipped with a diesel particulate filter (DPF) were studied in one set of standard primary and secondary dilution tunnels with varied dilution ratios. Particle size distribution data, during steady-state engine operation, were collected using a Cambustion DMS500 Fast Particulate Spectrometer. Measurements were made at four positions that spanned the tunnel cross section after the mixing orifice plate for the primary dilution tunnel and at the outlet of the secondary dilution tunnel.
Technical Paper

Determination of In-Use Brake-Specific Emissions from Off-Road Equipment Powered by Mechanically Controlled Diesel Engines

2002-05-06
2002-01-1756
Exhaust emissions from off-highway diesel engines are a significant contributor of both oxides of nitrogen (NOx) and particulate matter (PM) to air inventories. Yet, emissions research activities aimed solely at the off-highway arena have been minimal - largely overshadowed by the extensive efforts directed toward the on-highway sector. However, with current trends indicating that the performance of these off-highway vehicles will become increasingly more scrutinized by federal regulatory agencies, augmentation of current research efforts will be necessary. The global objective for this study was to collect vehicle activity information for diesel-powered off-highway vehicles while they were operated in the field. Engine speed and raw exhaust CO2 concentrations were recorded and then used to create engine dynamometer test cycles. The engine was exercised according to these cycles in the laboratory so that the mass emissions rates of exhaust gas pollutants could be measured.
Technical Paper

Measurement of In-Use, On-Board Emissions from Heavy-Duty Diesel Vehicles:Mobile Emissions Measurement System

2001-09-24
2001-01-3643
Emissions tests for heavy-duty diesel-fueled vehicles are normally performed using an engine dynamometer or a chassis dynamometer. Both of these methods generally entail the use of laboratory-grade emissions measurement instrumentation, a CVS system, an environment control system, a dynamometer, and associated data acquisition and control systems. The results obtained from such tests provide a means by which engines may be compared to the emissions standards, but may not be truly indicative of an engine's in-vehicle performance while operating on the road. An alternative to such a testing methodology would be to actively record the emissions from a vehicle while it was operating on-road. A considerable amount of discussion has been focused on the development of on-road emissions measurement systems (OREMS) that would provide for such in-use emissions data collection.
Technical Paper

The Influence of High Reactivity Fuel Properties on Reactivity Controlled Compression Ignition Combustion

2017-09-04
2017-24-0080
Reactivity controlled compression ignition (RCCI) is a form of dual-fuel combustion that exploits the reactivity difference between two fuels to control combustion phasing. This combustion approach limits the formation of oxides of nitrogen (NOX) and soot while retaining high thermal efficiency. The research presented herein was performed to determine the influences that high reactivity (diesel) fuel properties have on RCCI combustion characteristics, exhaust emissions, fuel efficiency, and the operable load range. A 4-cylinder, 1.9 liter, light-duty compression-ignition (CI) engine was converted to run on diesel fuel (high reactivity fuel) and compressed natural gas (CNG) (low reactivity fuel). The engine was operated at 2100 revolutions per minute (RPM), and at two different loads, 3.6 bar brake mean effective pressure (BMEP) and 6 bar BMEP.
Technical Paper

Fresh and Aged SCRT Systems Retrofitted on a MY 1998 Class-8 Tractor: Investigation on In-use Emissions

2011-09-11
2011-24-0175
In order to comply with stringent 2010 US-Environmental Protection Agency (EPA) on-road, Heavy-Duty Diesel (HDD) emissions regulations, the Selective Catalytic Reduction (SCR) aftertreatment system has been judged by a multitude of engine manufacturers as the primary technology for mitigating emissions of oxides of nitrogen (NOx). As virtually stand-alone aftertreatment systems, SCR technology further represents a very flexible and efficient solution for retrofitting legacy diesel engines as the most straightforward means of cost-effective compliance attainment. However, the addition of a reducing agent injection system as well as the inherent operation limitations of the SCR system due to required catalyst bed temperatures introduce new, unique problems, most notably that of ammonia (NH₃) slip.
Technical Paper

Characteristics of Exhaust Emissions from a Heavy-Duty Diesel Engine Retrofitted to Operate in Methane/Diesel Dual-Fuel Mode

2013-09-08
2013-24-0181
The need for a cleaner and less expensive alternative energy source to conventional petroleum fuels for powering the transportation sector has gained increasing attention during the past decade. Special attention has been directed towards natural gas (NG) which has proven to be a viable option due to its clean-burning properties, reduced cost and abundant availability, and therefore, lead to a steady increase in the worldwide vehicle population operated with NG. The heavy-duty vehicle sector has seen the introduction of natural gas first in larger, locally operated fleets, such as transit buses or refuse-haulers. However, with increasing expansion of the NG distribution network more drayage and long-haul fleets are beginning to adopt natural gas as a fuel.
Technical Paper

Greenhouse Gas Emissions of MY 2010 Advanced Heavy Duty Diesel Engine Measured Over a Cross-Continental Trip of USA

2013-09-08
2013-24-0170
The study was aimed at assessing in-use emissions of a USEPA 2010 emissions-compliant heavy-duty diesel vehicle powered by a model year (MY) 2011 engine using West Virginia University's Transportable Emissions Measurement System (TEMS). The TEMS houses full-scale CVS dilution tunnel and laboratory-grade emissions measurement systems, which are compliant with the Code of Federal Regulation (CFR), Title 40, Part 1065 [1] emissions measurement specifications. One of the specific objectives of the study, and the key topic of this paper, is the quantification of greenhouse gas (GHG) emissions (CO2, N2O and CH4) along with ammonia (NH3) and regulated emissions during real-world operation of a long-haul heavy-duty vehicle, equipped with a diesel particulate filter (DPF) and urea based selective catalytic reduction (SCR) aftertreatment system for PM and NOx reduction, respectively.
Technical Paper

Number Concentration and Size Distributions of Nanoparticle Emissions during Low Temperature Combustion using Fuels for Advanced Combustion Engines (FACE)

2014-04-01
2014-01-1588
Due to tightening emission legislations, both within the US and Europe, including concerns regarding greenhouse gases, next-generation combustion strategies for internal combustion diesel engines that simultaneously reduce exhaust emissions while improving thermal efficiency have drawn increasing attention during recent years. In-cylinder combustion temperature plays a critical role in the formation of pollutants as well as in thermal efficiency of the propulsion system. One way to minimize both soot and NOx emissions is to limit the in-cylinder temperature during the combustion process by means of high levels of dilution via exhaust gas recirculation (EGR) combined with flexible fuel injection strategies. However, fuel chemistry plays a significant role in the ignition delay; hence, influencing the overall combustion characteristics and the resulting emissions.
Technical Paper

Investigating the Potential of Waste Heat Recovery as a Pathway for Heavy-Duty Exhaust Aftertreatment Thermal Management

2015-04-14
2015-01-1606
Heavy-duty diesel (HDD) engines are the primary propulsion source for most heavy-duty vehicle freight movement and have been equipped with an array of aftertreatment devices to comply with more stringent emissions regulations. In light of concerns about the transportation sector's influence on climate change, legislators are introducing requirements calling for significant reductions in fuel consumption and thereby, greenhouse gas (GHG) emission over the coming decades. Advanced engine concepts and technologies will be needed to boost engine efficiencies. However, increasing the engine's efficiency may result in a reduction in thermal energy of the exhaust gas, thus contributing to lower exhaust temperature, potentially affecting aftertreatment activity, and consequently rate of regulated pollutants. This study investigates the possible utilization of waste heat recovered from a HDD engine as a means to offset fuel penalty incurred during thermal management of SCR system.
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