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Ultra-high injection pressures, as well as flash-boiling occurrence, are among the most important research fields recently explored for improving Gasoline Direct Injection (GDI) engine performance. Both of them play a key role in the enhancement of the air/fuel mixing process, in the reduction of tailpipe pollutant emissions, as well as in the investigation of new combustion concepts. Injector manufacturers are even more producing devices with ultra-high injection pressures capable of working with flashing sprays. Flash-boiling of fuel sprays occurs when a super-heated fuel is discharged into an environment whose pressure is lower than the saturation pressure of the fuel and can dramatically alter spray formation due to complex two-phase flow effects and rapid droplet vaporization. In GDI engines, typically, it occurs during the injection process when high fuel temperatures make its saturation pressures higher than the in-cylinder one.