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Natural gas, biogas, and biomethane are attractive fuels for compressed natural gas (CNG) engines because of their beneficial physical and chemical characteristics. This paper examines three combustion modes - homogeneous stoichiometric, homogeneous lean burn, and stratified combustion - in an optical single cylinder engine with a gas direct injection system operating with an injection pressure of 18 bar. The combustion process in each mode was characterized by indicated parameters, recording combustion images, and analysing combustion chemiluminescence emission spectra. Pure methane, which is the main component of CNG (up to 98%) or biomethane (> 98 %), was used as the fuel. Chemiluminescence emission spectrum analysis showed that OH* and CN* peaks appeared at their characteristic wavelengths in all three combustion modes. The peak of OH* and broadband CO2* intensities were strongly dependent on the air/fuel ratio conditions in the cylinder.

To assist efforts reducing harmful emissions from internal combustion engines, particulate formation was investigated in a compressed natural gas (CNG) Direct Injection single-cylinder SI engine in warm-up conditions. This involved tests at low engine speed and load, with selected engine coolant temperatures ranging from 15 to 90 °C, and use of a gasoline direct injection (GDI) system as a standard reference system. Total particulate number (PN), their size distribution, standard emissions, fuel consumption and rate of heat release were analyzed, and an endoscope with high-speed video imaging was used to observe combustion luminescence and soot formation-related phenomena. The results show that PN was strongly influenced by changes in coolant water temperature in both the CNG DI and GDI systems. However, the CNG DI engine generated 1 to 2 orders of magnitude lower PN than the GDI system at all tested temperatures.