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In order to determine the usefulness of coconut and palm oil biodiesels as alternative diesel fuel, the fuel properties, the combustion characteristics and the exhaust emissions were investigated. Therefore, the methyl esters of coconut, palm and rapeseed oils (CME, PME and RME) and the ethyl ester of palm and rapeseed oils (PEE and REE) were processed and tested using a DI diesel engine. From the experimental results, the thermal efficiency of CME is almost the same as the other test fuels and CME has the lowest HC, CO, NOx and smoke emissions among the test fuels. Also PEE has the same ignitibility as PME and the exhaust emissions of PEE are almost the same as PME. From this investigation, we can say that CME and PEE are favorable alternative diesel fuels to substitute for petroleum based diesel fuel.

Emulsified biodiesel has lower NOx and Smoke emissions from diesel engines compared with biodiesel. Emulsifier is needed to produce emulsification fuel. In this study, it has been clarified that the 15 wt% water emulsified biodiesel without adding any emulsifier can be produced. From the experimental results for a DI diesel engine, the fuel without emulsifier addition has shorter ignition delay and lower CO, HC, Smoke and Aclorein emissions compared with emulsified biodiesel with adding 0.1 wt% of crude glycerin, a by-product in the transesterification of biodiesel production process, as an emulsifier. There is no significant difference in the effect of the Sauter mean diameter of emulsified water particle on emulsified biodiesel combustion and emission characteristics in the range from 30 to 170 μm. Also, by adding 3 wt% of crude glycerin to biodiesel, the ignition delay of biodiesel becomes longer and the CO, HC and Smoke emissions increase.

In order to improve the cold flow properties of coconut oil biodiesel and to reduce the lifecycle CO2 emission by using bio-alcohol at biodiesel manufacturing, varying the types of alcohol used at transesterification was examined. The pour point of coconut oil ester decreases as the carbon number of alcohol increases. Among 5 ester fuels, the pour point of coconut oil isobutyl ester (CiBE) made from isobutanol is lowest, −12.5 °C, compared to that of coconut oil methyl ester (CME), highest, −5 °C. The pour point of coconut oil 1-butyl ester (CBE) is −10 °C, second lowest. Furthermore, CBE, CiBE, CME and JIS No.2 diesel fuel (gas oil) were tested using a DI diesel engine. CBE and CiBE have shorter ignition delay compared to the gas oil although slightly longer than CME. CBE and CiBE have the same thermal efficiency and NOx emissions compared to the gas oil. HC, CO and Smoke emissions of coconut oil ester fuels slightly increase when the ester molecule carbon number increases.

The diesel combustion characteristics and the exhaust emissions of biodiesel are affected by the composition of fatty acid methyl esters (FAMEs). In this study, the combustion characteristics and the exhaust emissions from single compositions of FAMEs, such as methyl palmitate, methyl oleate and the others, are investigated by using a single cylinder DI diesel engine. Experimental five FAME fuels are neat methyl oleate and the rest are blended mixtures based on methyl oleate. From the experimental results, the ignition delays of saturated FAMEs decrease with longer straight chain of the hydrocarbon molecules while in the same carbon number FAMEs, the ignition delays increase by increasing carbon-carbon double bonds. The break thermal efficiencies of the five FAME fuels and the gas oil are almost the same.