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Biodiesel is a renewable fuel which can be used as a direct replacement for fossil Diesel fuel as a calorific source in Diesel Engines. It consists of fatty acid mono-alkyl esters, which are produced by the trans-esterification reaction of plant oils with monohydric alcohols. The Plant oils and alcohols can both be derived from biomass, giving this fuel the potential for a sustainable carbon dioxide neutral life-cycle, which is an important quality with regard to avoiding the net emission of anthropogenic greenhouse gases. Depending on its fatty ester composition, Biodiesel can have varying physical and chemical properties which influence its combustion behaviour in a Diesel engine. It has been observed by many researchers that Biodiesel can sometimes lead to an increase in emissions of oxides of nitrogen (NOx) compared to fossil Diesel fuel, while emitting a lower amount of particulate mass.

Synthetic bio-fuels, which can be obtained through the gasification of biomass into synthesis gas and the subsequent catalytic reaction of the synthesis gas into liquid fuel molecules, could play a key-role in providing a sustainable source of automotive fuels during the coming decades. This paper presents an attempt to understand the effect of molecular structure of potential oxygenated synthetic bio-fuel molecules of different structure on the diesel combustion process in both stratified and homogeneous combustion modes. Specifically, the effects of molecular structure on the energy release rates, gaseous exhaust emissions and the sub-micron particulate matter distribution were examined. The experiments were carried out on a single-cylinder direct-injection diesel engine using a specially adapted common-rail fuel-system which allowed the injection of small single-molecule fuel samples at high pressure.

For a spark-ignition engine, the parasitic loss suffered as a result of conventional throttling has long been recognised as a major reason for poor part-load fuel efficiency. While lean, stratified charge, operation addresses this issue, exhaust gas aftertreatment is more challenging compared with homogeneous operation and three-way catalyst after-treatment. This paper adopts a different approach: homogeneous charge direct injection (DI) operation with variable valve actuations which reduce throttling losses. In particular, low-lift and early inlet valve closing (EIVC) strategies are investigated. Results from a thermodynamic single cylinder engine are presented that quantify the effect of two low-lift camshafts and one standard high-lift camshaft operating EIVC strategies at four engine running conditions; both, two- and single-inlet valve operation were investigated. Tests were conducted for both port and DI fuelling, under stoichiometric conditions.

Controlled Auto-Ignition (CAI) combustion has been achieved in a production type 4-stroke multi-cylinder gasoline engine. The engine was based on a Ford 1.7L Zetec-SE 16V engine with a compression ratio of 10.3, using substantially standard components modified only in design dimensions to control the gas exchange process in order to significantly increase the trapped residuals. The engine was also equipped with Variable Cam Timing (VCT) on both the intake and exhaust camshafts. It was found that the largely increased trapped residuals alone were sufficient to achieve CAI in this engine and with VCT, a range of loads between 0.5 and 4 bar BMEP and engine speeds between 1000 and 3500 rpm were mapped for CAI fuel consumption and exhaust emissions. The measured CAI results were compared with those of Spark Ignition (SI) combustion in the same engine but with standard camshafts at the same speeds and loads.

A quantitative relationship between diesel soot oxidation rate and oxidation temperature and oxygen partial pressure was investigated by burning the diesel exhaust soot particles in a controlled flat flame supplied with methane/air/oxygen/nitrogen mixtures. The oxidation temperature and the oxygen partial pressure were controlled in the ranges of 1530 to 1820 K and 0.01 to 0.05 atm (1atm = 1.01325 bar) respectively. Soot particle size distribution measurements were achieved with transmission electron microscopy (TEM) for particle samples that were collected on copper grids at different positions along the flame centerline. Oxidation periods were determined by means of laser Doppler anemometry (LDA). The experimental results showed that the experimental oxidation rates fall between the values predicted by the Nagle and Strickland-Constable formula and those by the Lee formula.

This paper presents results from an experimental programme researching the in-cylinder conditions necessary to obtain homogenous CAI (or HCCI) combustion in a 4-stroke engine. The fuels under investigation include three blends of Unleaded Gasoline, a 95 RON Primary Reference Fuel, Methanol, and Ethanol. This work concentrates on establishing the CAI operating range with regard to Air/Fuel ratio and Exhaust Gas Re-circulation and their effect on the ignition timing, combustion rate and variability, Indicated thermal efficiency, and engine-out emissions such as NOx. Detailed maps are presented, defining how each of the measured variables changes over the entire CAI region. Results indicate that the alcohols have significantly higher tolerance to dilution than the hydrocarbon fuels tested. Also, variations in Gasoline blend have little effect on any of the combustion parameters measured.

Controlled Auto-Ignition (CAI) combustion was realised in a production type 4-stroke 4-cylinder gasoline engine without intake charge heating or increasing compression ratio. The CAI engine operation was achieved using substantially standard components modified only in camshafts to restrict the gas exchange process The engine could be operated with CAI combustion within a range of load (0.5 to 4 bar BMEP) and speed (1000 to 3500 rpm). Significant reductions in both specific fuel consumption and CO emissions were found. The reduction in NOx emission was more than 93% across the whole CAI range. Though unburned hydrocarbons were higher under the CAI engine operation. In order to evaluate the potential of the CAI combustion technology, the European NEDC driving cycle vehicle simulation was carried out for two identical vehicles powered by a SI engine and a CAI/SI hybrid engine, respectively.

The effects of Air/Fuel (A/F) ratios and Exhaust Gas Re-Circulation (EGR) rates on Homogeneous Charge Compression Ignition (HCCI) combustion of n-heptane have been experimentally investigated. The experiments were carried out in a single-cylinder, 4-stroke and variable compression-ratio engine equipped with a port fuel injector. Investigations concentrate on the HCCI combustion of n-heptane at different A/F ratios, EGR rates and their effects on knock limit, engine load, combustion variability, and engine-out emissions such as NOx, CO, and unburned HC. Variations of auto-ignition timings and combustion durations in the two-stage combustion process are analyzed in detail. Results show that HCCI combustion with a diesel type fuel can be implemented at room temperature with a conventional diesel engine compression-ratio. However, its knock limit occurs at very high A/F ratios, although high EGR rates can be tolerated.

The conversion of lignocellulosic biomass to liquid fuels presents an alternative to the current production of renewable fuels for IC engines from food crops. However, realising the potential for reductions in net CO2 emissions through the utilisation of, for example, waste biomass for sustainable fuel production requires that energy and resource inputs into such processes be minimised. This work therefore investigates the combustion and emission characteristics of five intermediate platform molecules potentially derived from lignocellulosic biomass: gamma-valerolactone (GVL), methyl valerate, furfuryl alcohol, furfural and 2-methyltetrahydrofuran (MTHF). The study was conducted on a naturally aspirated, water cooled, single cylinder spark-ignition engine. Each of the platform molecules were blended with reference fossil gasoline at 20 % wt/wt.

There is a great deal of interest in new technologies to assist in reducing the CO2 output of passenger vehicles, as part of the drive to meet the limits agreed by the EU and the European Automobile Manufacturer's Association ACEA, itself a result of the Kyoto Protocol. For the internal combustion engine, the most promising of these include gasoline direct injection, downsizing and fully variable valve trains. While new types of spray-guided gasoline direct injection (GDI) combustion systems are finally set to yield the level of fuel consumption improvement which was originally promised for the so-called ‘first generation’ wall- and air-guided types of GDI, injectors for spray-guided combustion systems are not yet in production to help justify the added complication and cost of the NOx trap necessary with a stratified combustion concept.

Reductions in fuel consumption, noise level, and pollutant emissions such as, Nitrogen Oxide (NOX) and Particulate Matter (PM), from direct-injection (DI) diesel engines are important issues in engine research. To achieve these reductions, many technologies such as high injection pressure, multiple injection, retarded injection timing, EGR, and high swirl ratio have been used in high-efficiency DI diesel engines in order to achieve combustion and emission control. However, each technology has its own advantages and disadvantages, and there is a very strong interaction between these methods when they are simultaneously used in the engine. This study presents a computational study of both the individual effect and their interactions of injection timing, EGR and swirl ratio separately and their interaction in a HSDI common rail diesel engine using the KIVA-3V code.

Improvements in the efficiency of internal combustion engines and the development of renewable liquid fuels have both been deployed to reduce exhaust emissions of CO2. An additional approach is to scrub CO2 from the combustion gases, and one potential means by which this might be achieved is the reaction of combustions gases with sodium borohydride to form sodium carbonate. This paper presents experimental studies carried out on a modern direct injection diesel engine supplied with a solution of dissolved sodium borohydride so as to investigate the effects of sodium borohydride on combustion and emissions. Sodium borohydride was dissolved in the ether diglyme at concentrations of 0.1 and 2 % (wt/wt), and tested alongside pure diglyme and a reference fossil diesel. The sodium borohydride solutions and pure diglyme were supplied to the fuel injector under an inert atmosphere and tested at a constant injection timing and constant engine indicated mean effective pressure (IMEP).