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Among the new low temperature combustion modes, Reactivity-Controlled Compression Ignition (RCCI) offers a low NOx-soot trade off (keeping a relatively high engine efficiency). Also, RCCI permits the introduction of a renewable fuel with a lower CO2 direct emission such as short-chains alcohols. For this work, methanol and diesel fuel were used as low and high reactivity fuels, respectively. A 1.3 L single-cylinder engine, with a cylinder volume usual in medium- and heavy-duty truck and bus engines, was used in this work. The engine was operated at an engine speed of 1600 rpm and 25% load (representing one of the 13-mode test on medium duty trucks), which results in an indicated mean effective pressure of 5.2 bar. The effects of methanol substitution ratio (MSR) at 20 and 35% on performance and pollutant emissions was investigated and compared to conventional diesel combustion (CDC).