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Journal Article

Effect of Temperature and Aeration on Fluid-Elastomer Compatibility

2013-04-08
2013-01-0652
To investigate the effect of aeration on fluid-elastomer compatibility, 4 types of elastomers were aged in three gear lubes. The four types of elastomers include a production fluorinated rubber (FKM) and production hydrogenated nitrile rubber (HNBR) mixed by the part fabricator, a standard low temperature flexible fluorinated rubber (FKM, ES-4) and a standard ethylene-acrylic copolymer (AEM, ES-7) mixed by SAE J2643 approved rubber mixer. The three gear lubes are Fluid a, Fluid b and Fluid c, where Fluid b is a modified Fluid with additional friction modifier, and Fluid c is friction modified chemistry from a different additive supplier. The aeration effect tests were performed at 125°C for 504 hours. The aerated fluid aging test was performed by introducing air into fluid aging tubes as described in General Motors Company Materials Specification GMW16445, Appendix B, side-by-side with a standard ASTM D471 test.
Technical Paper

Compatibility Study of Fluorinated Elastomers in Automatic Transmission Fluids

2008-06-23
2008-01-1619
A compatibility study was conducted on fluorinated elastomers (FKM and FEPM) in various Automatic Transmission Fluids (ATF). Representative compounds from various FKM families were tested by three major FKM raw material producers - DuPont Performance Elastomers (DPE), Dyneon and Solvay. All involved FKM compounds were tested in a newly released fluid (ATF-A) side-by-side with conventional transmission fluids, at 150°C for various time intervals per ASTM D471. In order to evaluate the fluid compatibility limits, some FKM's were tested as long as 3024 hrs, which is beyond the normal service life of seals. Tensile strength and elongation were monitored as a function of ATF exposure time. The traditional dipolymers and terpolymers showed poor resistance to the new fluid (ATF-A). Both types demonstrated significant decreases in strength and elongation after extended fluid exposure at 150°C.
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