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A possible environmental assessment of sustainable vehicular transport is based on a comparative analysis through the LCA Life Cycle Analysis methodology of the entire vehicle’s life cycle. For this purpose, it could contribute to the choices of political decision-makers and investors in the sector of large infrastructure and industrial works. Therefore, the LCA activity is of fundamental importance for the estimation and analysis of the economic and social impacts through the comparative analysis of technological solutions in scenarios of “accelerated technological evolution” and/or “sustainable mobility”. The study could be designed for different vehicle segments to evaluate their efficiency and overall environmental sustainability also related to current social and political scenarios. Couples with electric and internal combustion vehicles of the same market segment and category may be compared.