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This article presents nondestructive neutron computed tomography (nCT) measurements of Diesel Particulate Filters (DPFs) as a method to measure ash and soot loading in the filters. Uncatalyzed and unwashcoated 200cpsi cordierite DPFs exposed to 100% biodiesel (B100) exhaust and conventional ultra low sulfur 2007 certification diesel (ULSD) exhaust at one speed-load point (1500 rpm, 2.6 bar BMEP) are compared to a brand new (never exposed) filter. Precise structural information about the substrate as well as an attempt to quantify soot and ash loading in the channel of the DPF illustrates the potential strength of the neutron imaging technique.

Diesel particulate samples were collected from a light duty engine operated at a single speed-load point with a range of biodiesel and conventional fuel blends. The oxidation reactivity of the samples was characterized in a laboratory reactor, and BET surface area measurements were made at several points during oxidation of the fixed carbon component of both types of particulate. The fixed carbon component of biodiesel particulate has a significantly higher surface area for the initial stages of oxidation, but the surface areas for the two particulates become similar as fixed carbon oxidation proceeds beyond 40%. When fixed carbon oxidation rates are normalized to total surface area, it is possible to describe the oxidation rates of the fixed carbon portion of both types of particulates with a single set of Arrhenius parameters. The measured surface area evolution during particle oxidation was found to be inconsistent with shrinking sphere oxidation.

An overall diesel engine and aftertreatment system model has been created that integrates diesel engine, exhaust system, engine emissions, and diesel particulate filter (DPF) models using MATLAB Simulink. The 1-D engine and exhaust system models were developed using WAVE. The engine emissions model combines a phenomenological soot model with artificial neural networks to predict engine out soot emissions. Experimental data from a light-duty diesel engine was used to calibrate both the engine and engine emissions models. The DPF model predicts the behavior of a clean and particulate-loaded catalyzed wall-flow filter. Experimental data was used to validate this sub-model individually. Several model integration issues were identified and addressed. These included time-step selection, continuous vs. limited triggering of sub-models, and code structuring for simulation speed. Required time-steps for different sub models varied by orders of magnitude.

Gasoline Direct Injection (GDI) is known to produce lower concentrations of smaller particulate matter (PM) compared to diesel combustion [1]. The lower concentration results in the absence of soot-cake formation on the filter channel wall and therefore filtration behavior deviates from the expected diesel particulate filter (DPF) performance. Therefore, studies of cake-less filtration regimes for smaller sized particulates is of interest for GDI PM mitigation. This work investigates the filtration efficiency of laboratory-generated particulates, representative of GDI-sized PM, in uncoated, commercial DPF cordierite substrates of varying porosities. Size-dependent particulate concentrations were measured using a Scanning Mobility Particle Sizer (SMPS), both upstream and downstream of the filters. By comparing these measured concentrations, the particle size-dependent filtration efficiency of filter samples was calculated.

The increasing number of gasoline direct injection (GDI) vehicles on the roads has drawn attention to their particulate matter (PM) emissions, which are greater both in number and mass than port fuel injected (PFI) spark ignition (SI) engines [1]. Regulations have been proposed and implemented to reduce exposure to PM, which has been shown to have negative impacts on both human health and the environment [2, 3]. Currently, the gasoline particulate filter (GPF) is the proposed method of reducing the amount of PM from vehicle exhaust, but modifications to improve the filtration efficiency (FE) and reduce the pressure drop across the filter are yet needed for implementation of this solution in on-road vehicles. This work evaluates the impacts of wall thickness and cell density on filtration efficiency and backpressure using a benchtop filtration system.

The objective of this book is to present a fundamental development of the science and engineering underlying the design of exhaust aftertreatment systems for automotive internal combustion engines. No pre-requisite knowledge of the field is required: our objective is to acquaint the reader, whom we expect to be new to the field of emissions control, with the underlying principles, control methods, common problems, and fuel effects on catalytic exhaust aftertreatment devices. We do this in hope that they can better understand the previous and current generations of emissions control, and improve upon them. This book is designed for the engineer, researcher, designer, student, or any combination of those, who is concerned with the control of automotive exhaust emissions. It includes discussion of theory and fundamentals applicable to hardware development.