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Electrochemical models of lithium ion batteries are today a standard tool in the automotive industry for activities related to the computer-aided engineering design, analysis, and optimization of energy storage systems for electrified vehicles. One of the challenges in the development or use of such models is the need of detailed information on the cell and electrode geometry or properties of the electrode and electrolyte materials, which are typically unavailable or difficult to retrieve by end-users. This forces engineers to resort to “hand-tuning” of many physical and geometrical parameters, using standard cell-level characterization tests. This paper proposes a method to provide information and data on individual electrode performance that can be used to simplify the calibration process for electrochemical models.

This paper benchmarks three different lithium-ion (Li-ion) battery voltage modelling approaches, a physics-based approach using an Extended Single Particle Model (ESPM), an equivalent circuit model, and a recurrent neural network. The ESPM is the selected physics-based approach because it offers similar complexity and computational load to the other two benchmarked models. In the ESPM, the anode and cathode are simplified to single particles, and the partial differential equations are simplified to ordinary differential equations via model order reduction. Hence, the required state variables are reduced, and the simulation speed is improved. The second approach is a third-order equivalent circuit model (ECM), and the third approach uses a model based on a Long Short-Term Memory Recurrent Neural Network (LSTM-RNN)). A Li-ion pouch cell with 47 Ah nominal capacity is used to parameterize all the models.