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This paper describes a thick film ZrO2 NOx sensor feasible for diesel and gasoline engine applications, and introduces modification items from the previous concept design.(1) The modification items comprise simplifying the sensing element design to reduce output terminals for package design and applying temperature control to the sensing element in order to minimize sensor performance dependency on gas temperature. The NOx sensor indicates a stable linear signal in proportion to NOx concentration in a wide range of temperature, A/F and NOx concentration as a practical condition on both gasoline and diesel engines. The NOx sensor shows a good response in hundred msec. and a sharp signal following NOx generation in a transient state as well. Besides, another type of a NOx sensor is proposed for low NOx measurement in a practical use, by an electromotive force(EMF) voltage instead of a pumping current.

This paper describes the design and operation of the multi-layered zirconia heated exhaust gas oxygen sensor having small-sized and sheet-shaped sensing element. This sensor uses an electrode modified with a rhodium catalyst and heater by means of the thick-film technique. This modification of an electrode's composition and construction affects the reaction on unburned components in exhaust gas as well as the sensor performance. By the addition of a rhodium catalyst, the zirconia exhaust gas oxygen sensor shows acute sensitivity and faster response properties in the transient state on emission component(NOx) generation, in such a way that these sensors show better emission control properties for reduction of NOx emission in current emission control systems. The addition of a rhodium catalyst reduces the green effect of sensor properties, and no significant change of emission control properties is observed after 50,000 equivalent miles using the engine dynamometer durability test.