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Biodiesel is a renewable fuel which can be used as a direct replacement for fossil Diesel fuel as a calorific source in Diesel Engines. It consists of fatty acid mono-alkyl esters, which are produced by the trans-esterification reaction of plant oils with monohydric alcohols. The Plant oils and alcohols can both be derived from biomass, giving this fuel the potential for a sustainable carbon dioxide neutral life-cycle, which is an important quality with regard to avoiding the net emission of anthropogenic greenhouse gases. Depending on its fatty ester composition, Biodiesel can have varying physical and chemical properties which influence its combustion behaviour in a Diesel engine. It has been observed by many researchers that Biodiesel can sometimes lead to an increase in emissions of oxides of nitrogen (NOx) compared to fossil Diesel fuel, while emitting a lower amount of particulate mass.

In recent years a new combustion phenomenon called Low-Speed Pre-Ignition (LSPI) occurred, which is the most important limiting factor to exploit further downsizing potential due to the associated peak pressures and thus the huge damage potential. In the past there were already several triggers for pre-ignitions identified, whereat engine oil seems to have an important influence. Other studies have reported that detached oil droplets from the piston crevice volume lead to auto-ignition prior to spark ignition. However, wall wetting and subsequently oil dilution and changes in the oil properties by impinging fuel on the cylinder wall seem to have a significant influence in terms of accumulation and detachment of oil-fuel droplets in the combustion chamber. For this reason, the influence of test fuels with different volatility were investigated in order to verify their influence on wall wetting, detachment and pre-ignition tendency.

An unmodified, conventionally fuelled, 2009 Class D vehicle with a 2.0L turbocharged gasoline direct injection engine was operated on a range of gasoline, gasoline-ethanol and gasoline-butanol fuel blends over NEDC drive cycles and WOT power curves on a chassis dynamometer. Engine performance, engine management system parameters and vehicle out emissions were recorded to investigate the response of a current state-of-the-art technology vehicle to various alcohol fuel blends. The vehicle fired on all fuels and was capable of adapting its long term fuelling trim to cope with the increased fuel flow demand for alcohol fuels up to E85. Over the NEDC tests, the volumetric fuel consumption was very strongly related to the calorific content of the fuel. CO and NOx emissions were largely unaffected for the mid alcohol blends, but CO emissions decreased and NOx emissions increased significantly for the high alcohol fuels. THC emissions were largely unaffected.

Toyota and BP have performed a collaborative study to understand the impact of fuel composition on the combustion and emissions of a prototype 1.8L lean boosted engine. The fuel matrix was designed to understand better the impact of a range of fuel properties on fundamental combustion characteristics including thermal efficiency, combustion duration, exhaust emissions and extension of lean limit. Most of the fuels in the test matrix were in the RON range of 96 - 102, although ethanol and other high octane components were used in some fuels to increase RON to the range 104 - 108. The oxygen content ranged from 2 - 28%, and constituents included biocomponents, combustion improving additives and novel blend components. Performance and emissions tests were conducted over a range of engine operating conditions. Thermal efficiency was mapped at stoichiometric and lean conditions, and the limit of lean combustion was established for different fuels.

The fuel effects on HCCI operation in a spark assisted direct injection gasoline engine are assessed. The low load limit has been extended with a pilot fuel injection during the negative valve overlap (NVO) period. The fuel matrix consists of hydrocarbon fuels and various ethanol blends and a butanol blend, plus fuels with added ignition improvers. The hydrocarbon fuels and the butanol blend do not significantly alter the high or the low limits of operation. The HCCI operation appears to be controlled more by the thermal environment than by the fuel properties. For E85, the engine behavior depends on the extent that the heat release from the pilot injected fuel in the NVO period compensates for the evaporative cooling of the fuel.

The performance aspect of gasoline combustion has traditionally been measured using Research Octane Number (RON) and Motor Octane Number (MON) which describe antiknock performance under different conditions. Recent literature suggests that MON is less important than RON in modern cars and a relaxation in the MON specification could improve vehicle performance, while also helping refiners in the production of gasoline. At the same time, for the same octane number change, increasing RON appears to provide more benefit to engine power and acceleration than reducing MON. It has also been suggested that there could be fuel efficiency benefits (on a tank to wheels basis) for specially adapted engines, for example, operating at higher compression ratio, on very high RON (100+). Other workers have advocated the use of an octane index (OI) which incorporates both RON and MON to give an indication of octane quality.

In an effort to reduce CO2 emissions, governments are increasingly mandating the use of various levels of biofuels. While this is strongly supported in principle within the energy and transportation industries, the impact of these mandates on the transport stock’s CO2 emissions and overall operating efficiency has yet to be fully explored. This paper provides information on studies to assess biodiesel influences and effects on engine performance, driveability, emissions and fuel consumption on state-of-the-art Euro IV compliant Toyota Avensis D4-D vehicles with DPNR aftertreatment systems. Two fuel matrices (Phases 1 & 2) were designed to look at the impact of fuel composition on vehicle operation using a wide range of critical parameters such as cetane number, density, distillation and biofuel (FAME) level and type, which can be found within the current global range of Diesel fuel qualities.