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Vehicular ammonia emissions are currently unregulated, even though ammonia is harmful for a variety of reasons, and the gas is classed as toxic. Ammonia emissions represent a serious threat to air quality, particularly in urban settings; an ammonia emissions limit may be introduced in future legislation. Production of ammonia within the cylinder has long been known to be very limited. However, having reached its light-off temperature, a three-way catalyst can produce substantial quantities of ammonia through various reaction pathways. Production of ammonia is symptomatic of overly reducing conditions within the three-way catalyst (TWC), and depends somewhat upon the particular precious metals used. Emission is markedly higher during periods where demand for engine power is higher, when the engine will be operating under open-loop conditions.

Ammonia is a reactive nitrogen compound (RNC - nitrogen-based gaseous molecules with multiple adverse impacts on human health and the biosphere). A three-way catalyst can produce substantial quantities of ammonia through various reaction pathways. This study presents a brief literature review, and presents experimental data on ammonia emissions from seven Euro 5 passenger cars, using different gasoline fuels and a CNG fuel. All vehicles were tested on a chassis dynamometer over the New European Driving Cycle. For six of the vehicles, ammonia was quantified directly at tailpipe (using two different analyzers); emissions from one vehicle were subjected to Fourier Transform Infra-Red (FTIR) analysis. Emissions of ammonia from these vehicles were generally low in comparison to other chassis dynamometer studies, perhaps attributable to the favorable laboratory test conditions and the age of the vehicles.