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Exhaust emissions of seventeen 2,3,7,8-substituted chlorinated dibenzo-p-dioxin/furan (CDD/F) congeners, tetra-octa CDD/F homologues, twelve WHO 2005 chlorinated biphenyls (CB) congeners, mono-nona CB homologues, and nineteen polycyclic aromatic hydrocarbons (PAHs) from a model year 2008 Cummins ISB engine equipped with aftertreatment including a diesel oxidation catalyst (DOC) and wall flow copper or iron urea selective catalytic reduction filter (SCRF) were investigated. These systems differ from a traditional flow through urea selective catalytic reduction (SCR) catalyst because they place copper or iron catalyst sites in close proximity to filter-trapped particulate matter. These conditions could favor de novo synthesis of dioxins and furans. The results were compared to previously published results of modern diesel engines equipped with a DOC, catalyzed diesel particulate filter (CDPF) and flow through urea SCR catalyst.

Thermal management of the exhaust has become important as exhaust catalyst systems are being added to heavy duty (HD) diesel engines. The HD certification cycle consists of a cold-start transient cycle followed by a twenty minute soak with the engine off and then another ‘hot’ transient cycle. The first half of the HD transient cycle represents urban driving and consequently the engine duty cycle is very low. The low duty cycle results in low exhaust temperatures that can challenge the performance of catalysts. The cycle then transitions to a highway simulation at high loads. The high loads require high catalyst efficiency. If the catalysts are below optimum temperature prior to this transition, they need to warm up very quickly to prevent excessive emissions slip. The twenty minute soak also provides opportunity for catalysts to experience a significant temperature drop prior to the ‘hot’ cycle.

Exhaust emissions were evaluated for four different catalytic exhaust emission control systems. Each system utilized a diesel oxidation catalyst, a metal-substrate partial-flow diesel particulate filter, an iron-exchanged or copper-exchanged Y-zeolite catalyst for urea selective catalytic reduction, and an ammonia slip catalyst. A 5.9-liter diesel truck engine was modified to match the exhaust conditions of a four-stroke diesel locomotive engine meeting the current Tier 2 locomotive emissions standards. NOx emissions, CO₂ emissions and exhaust temperatures were matched to the eight locomotive "throttle notch" power settings while exhaust mass flow was maintained near a constant fraction of locomotive exhaust mass flow for each "throttle notch" position. Regulated and unregulated exhaust emissions were measured over a steady-state test cycle for each of the four systems at low hours and following accelerated thermal aging and accelerated oil ash accumulation.

Multiple areas in the U.S. continue to struggle with achieving National Ambient Air Quality Standards for ozone. These continued issues highlight the need for further reductions in NOX emission standards in multiple industry sectors, with heavy-duty on-highway engines being one of the most important areas to be addressed. Starting in 2014, CARB initiated a series of technical demonstration programs aimed at examining the feasibility of achieving up to a 90% reduction in tailpipe NOX, while at the same time maintaining a path towards GHG reductions that will be required as part of the Heavy-Duty Phase 2 GHG program. These programs culminated in the Stage 3 Low NOX program, which demonstrated low NOX emissions while maintaining GHG emissions at levels comparable to the baseline engine.