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The finite nature and instability of fossil fuel supply has led to an increasing and enduring investigation demand of alternative and regenerative fuels. An investigation program is carried out to explore the potential of tailor made fuels to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. In this paper, fundamental results of the Diesel engine relevant combustion are presented. To enable optimum engine performance a range of different reference fuels have been investigated. The fundamental effects of different physical and chemical properties on emission formation and engine performance are investigated using a thermodynamic diesel single cylinder research engine and an optically-accessible combustion vessel. Depending on the chain length and molecular structure, fuel compounds vary in cetane number, boiling temperature etc. Therefore, different hydrocarbons including n-heptane, n-dodecane, and l-decanol were investigated.

Maintaining low NOx emissions over the operating range of diesel engines continues to be a major issue. However, optical measurements of nitric oxide (NO) are lacking particularly in the core of diesel jets, i.e. in the region of premixed combustion close to the spray axis. This is basically caused by severe attenuation of both the laser light and fluorescent emission in laser-induced fluorescence (LIF) applications. Light extinction is reduced by keeping absorption path lengths relatively short in this work, by investigating diesel jets in a combustion vessel instead of an engine. Furthermore, the NO-detection threshold is improved by conducting 1-d line measurements instead of 2-d imaging. The NO-LIF data are corrected for light attenuation by combined LIF and spontaneous Raman scattering. The quantified maximum light attenuation is significantly lower than in comparable previous works, and its wavelength dependence is surprisingly weak.

Tailor-made multi-component fuels are currently being developed for advanced Diesel engines. Accordingly, there is renewed interest in the detailed evaporation characteristics of such multi-component fuels, in particular because soot formation in reacting Diesel sprays generally depends on the mixture formation upstream of the lift-off location. It is also well established that fuel components with different volatility are generally not coevaporative due to fractional distillation in the mixture formation process of spark-ignition engines, but it is not clear if this holds for Diesel-like sprays, in which evaporation and mixing are expected to be more rapid. Unfortunately, little work has been done in this field, and some of the previous results appear to be contradictory. This paper presents a new laser diagnostic approach, which yields the vapor-phase concentrations of two fuel components simultaneously in Diesel-like sprays.

With increasing interest in new biofuel candidates, 1-octanol and di-n-butylether (DNBE) were presented in recent studies. Although these molecular species are isomers, their properties are substantially different. In contrast to DNBE, 1-octanol is almost a gasoline-type fuel in terms of its auto-ignition quality. Thus, there are problems associated with engine start-up for neat 1-octanol. In order to find a suitable glow-plug position, mixture formation is studied in the cylinder under almost idle operating conditions in the present work. This is conducted by planar laser-induced fluorescence in a high-speed direct-injection optical diesel engine. The investigated C8-oxygenates are also significantly different in terms of their evaporation characteristics. Thus, in-cylinder mixture formation of these two species is compared in this work, allowing conclusions on combustion behavior and exhaust emissions.

Downsizing of highly-boosted spark-ignition (SI) engines is limited by pre-ignition, which may lead to extremely strong knocking and severe engine damage. Unfortunately, the concerning mechanisms are generally not yet fully understood, although several possible reasons have been suggested in previous research. The primary objective of the present paper is to investigate the influence of molecular bio-fuel structure on the locations of pre-ignition in a realistic, highly-charged SI engine at low speed by state-of-the-art optical measurements. The latter are conducted by using a high-sensitivity UV endoscope and an intensified high-speed camera. Two recently tested bio-fuels, namely tetrahydro-2-methylfuran (2-MTHF) and 2-methylfuran (2-MF), are investigated. Compared to conventional fuels, they have potential advantages in the well-to-tank balance. In addition, both neat ethanol and conventional gasoline are used as fuels.