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Exhaust emissions were measured under real world urban driving conditions using a set of in-vehicle FTIR emission measurement system, which is able to measure 65 emission components simultaneously at a rate of 0.5 Hz. The test vehicle was a modern EURO4 emission compliant SI car equipped with temperature measurement along the exhaust pipe across the catalyst so as to match thermal characteristics to emission profiles. A free flow urban driving cycle was used for the test and four repeated journeys were conducted. The results were compared to EU emissions legislation. The results show that the warm up of the lubricating oil needed 15 minutes. The TWC needed about 200 seconds to reach full conversion efficiency. CO, THC and NOx emissions exceeded the EURO4 exhaust emission legislation. CO2 emissions were well above the type approval value of this vehicle.