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It has been observed that intermittent injection leads to improved spray characteristics in terms of mixing and gas entrainment. Although some experimental work has been carried out in the past, the disintegration mechanisms that govern the breakup of intermittent jets remain unknown. In this paper we have carried out a systematic numerical analysis of the breakup of pulsated jets under different injection conditions. More specifically, the duty cycle (share of active injection during one cycle) is varied, while the total cycle time is kept constant. The advection of the liquid phase is handled through the Volume of Fluid approach and, in order to provide an accurate, yet computationally acceptable, resolution of the turbulent structures, the implicit Large Eddy Simulation has been adopted. The results show that the primary disintegration results from a combination of stretching, collision and aerodynamic interaction effects.