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Ethanol fuelled homogenous charge compression ignition engine (HCCI) offers a better alternative to tackle the problems of achieving higher engine efficiency and lower emissions. Numerical simulations were carried out for a HCCI engine fueled with ethanol by stochastic reactor model using newly developed reduced ethanol oxidation mechanism consists of 47 species and 272 reactions. Reduced mechanism used in this study is validated by measured engine cylinder pressure curves and measured ignition delays in constant volume reactors in the previous study. Simulations are conducted for engine speeds ranging from 1000 to 3000 rpm at different intake temperatures (range 365-465 K) by varying the air-fuel ratio. Parametric study for combustion and emission characteristics is conducted and engine maps are developed at most efficient inlet temperatures. The HCCI operating range is defined using combustion efficiency (>85%) and maximum pressure rise rate (<5 MPa/ms).