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In this study, the influence of fuel premixing ratio (PMR) on the performance, combustion, and emission characteristics of dual-fuel operation in the compression ignition (CI) engine have been investigated. For dual fuel operation in CI-engine, two fuels of different reactivity are utilized in the same combustion cycle. In this study, low reactivity fuels (gasoline/butanol) is injected into the intake manifold, and high reactivity fuel (diesel) is directly injected into the cylinder. To operate the conventional CI engine in dual-fuel mode, the intake manifold of the engine was modified and a solenoid based port fuel injector was installed. A separate port fuel injector controller was used for injecting the gasoline or butanol. Suitable instrumentation was used to measure in-cylinder pressure and exhaust gas emissions. Experiments were performed by maintaining the constant fuel energy at different fuel PMR for different engine loads at constant engine speed.