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The majority of unburned hydrocarbon emissions from vehicles occur during cold start operation of the vehicle before the catalyst system has heated to the point where it has reached high operating efficiency. One promising technology to reduce cold start hydrocarbon emissions is the catalyzed hydrocarbon trap. This paper presents the results of a vehicle, laboratory, and modeling study of the performance of this relatively new type of catalyst. A procedure to evaluate trap performance in the laboratory is presented that correlates well with trap performance on a vehicle. Additionally, a mathematical model of the catalyzed hydrocarbon trap is presented. This model utilizes laboratory determined parameters to calibrate the model for specific catalyzed hydrocarbon trap formulations to simulate the performance of that formulation on a vehicle. Data is presented that shows the model agrees well with vehicle data during the bag 1 portion of the Federal Test Procedure.

Catalyzed hydrocarbon traps have shown promise in reducing cold-start tailpipe hydrocarbon emissions from gasoline powered vehicles. In this paper, we report the use of catalyzed hydrocarbon trap technology to reduce the non-methane hydrocarbon emissions from a flex-fuel vehicle that can operate on fuel mixtures ranging from pure gasoline to 85% ethanol/15% gasoline. We have found that hydrocarbon traps show a substantially greater reduction in hydrocarbon emissions when used with ethanol fuel than with gasoline. We present laboratory and vehicle test results that show that tailpipe non-methane hydrocarbon emissions from a flex-fuel vehicle can be reduced by 43% when using 85% ethanol/15% gasoline fuel and 16% when using gasoline fuel from a baseline exhaust system using a three-way catalyst. These results were obtained using a catalyzed hydrocarbon trap specifically formulated for use with ethanol fuel.