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Abnormal ignition, especially preignition, in gasoline engines has been a phenomenon that has been reported for many decades, going back to at least the 1920s in the literature. In the last 10 years, another abnormal combustion issue that has been deemed as preignition has been observed and documented. It is not clear if these issues from the early years are related or similar in nature to the present ones. Was the issue solved and now back again? Did changes occur in engine designs that caused this abnormal combustion phenomena to reappear? This paper serves as a review of literature from the 1920s through the 2000s on instances of abnormal ignition by fuel and lubricant derivatives, and what has been observed and learned. The different terms used to describe these phenomena are defined and clarified. Trends observed with the mechanisms and causes are discussed.

Several oxygenates have been proposed and tested for use with diesel fuel as a means of reducing exhaust emissions. This paper examines dimethyl ether (DME), which can be produced in many ways including via Air Products and Chemicals, Inc's Liquid Phase Technology (LPDME ™). Modest additions of DME into diesel fuel (2 wt.% oxygen) showed reductions in particulate matter emissions, but the previous data reported by the author from a multicylinder Navistar 7.3L Turbodiesel engine were scattered. In this study, experiments were performed on a multi-cylinder Navistar 7.3L Turbodiesel engine to repeatably confirm and extend the observations from the earlier studies. This is an important step in not only showing that the fuel does perform well in an engine with minor modifications to the fuel system, but also showing that DME can give consistent, significant results in lowering emissions.

Dimethyl Ether (DME) is a potential ultra-clean diesel fuel. Its unique characteristics require special handling and accommodation of its low viscosity and low lubricity. In this project, DME was blended with diesel fuel to provide sufficient viscosity and lubricity to permit operation of a 7.3 liter turbodiesel engine in a campus shuttle bus with minimal modification of the fuel injection system. A pressurized fuel delivery system was added to the existing common rail injection system on the engine, allowing the DME-diesel fuel blend to be circulated through the rail at pressures above 200 psig keeping the DME in the liquid state. Fuel exiting the rail is cooled by finned tubed heat exchangers and recirculated to the rail using a gear pump. A modified LPG tank (for use on recreational vehicles) stores the DME- diesel fuel blend onboard the shuttle bus.

In this work, an experimental and analysis methodology was developed to evaluate the preignition propensity of fuels and engine operating conditions in an SI engine. A heated glow plug was introduced into the combustion chamber to induce early propagating flames. As the temperature of the glowplug varied, both the fraction of cycles experiencing these early flames and the phasing of this combustion in the engine cycle varied. A statistical methodology for assigning a single-value to this complex behavior was developed and found to have very good repeatability. The effects of engine operating conditions and fuels were evaluated using this methodology. While this study is not directly studying the so-called stochastic preignition or low-speed preignition problem, it studies one aspect of that problem in a very controlled manner.

The effects of aromatic content and octane rating of gasoline fuels on stochastic pre-ignition (SPI) behaviors were investigated at typical operating conditions using a modern 2.0 L turbocharged engine. In-cylinder pressure time history measurements made during a speed-load test sequence designed to stimulate SPI were used to determine both the frequency of SPI occurrence and the in-cylinder peak pressure during such events. Six fuels were tested with varying levels of aromatic content (15 - 35% by vol.) and two octane rating levels (∼88 & 94 anti-knock index). The engine was operated using a production-intent calibration with equivalence ratio near one. Pressure and temperature in the intake manifold were held constant near two bar and 35°C respectively. Significant SPI activity was observed, with abnormal event frequencies up to ∼1 SPI event per 1,000 engine cycles and in-cylinder peak pressures up to ∼200 bar.

Stochastic Preignition (SPI) is an abnormal combustion phenomenon for internal combustion engines (ICE), which has been a significant impact to automotive companies developing high efficiency, turbocharged, direct fuel injection, spark ignited engines. It is becoming clearer what fuel properties are related to the cause of SPI, whether directly with fuel preparation in the cylinder, or mechanisms related to the deposit build-up which contributes to initial and follow-on SPI events. The purpose of this paper is to provide a summary of global market gasoline fuel properties with special attention given to properties and specific compounds from the fuel and fuel additives that can contribute to SPI and the deposit build-up in engines. Based on a review of the global fuel quality, it appears that the fuel quality has not caught up to meet the technology requirements for fuel economy from modern technology engines.

Gasoline Direct Injection (GDI) has become the preferred technology for spark-ignition engines resulting in greater specific power output and lower fuel consumption, and consequently reduction in CO2 emission. However, GDI engines face a substantial challenge in meeting new and future emission limits, especially the stringent particle number (PN) emissions recently introduced in Europe and China. Studies have shown that the fuel used by a vehicle has a significant impact on engine out emissions. In this study, nine fuels with varying chemical composition and physical properties were tested on a modern turbo-charged side-mounted GDI engine with design changes to reduce particulate emissions. The fuels tested included four fuels meeting US certification requirements; two fuels meeting European certification requirements; and one fuel meeting China 6 certification requirements being proposed at the time of this work.

Two of the goals of the Penn State FutureTruck project were to reduce the emissions of the hybrid electric Ford Explorer to ULEV or lower, and improve the fuel economy by 25% over the stock vehicle. The hybrid electric vehicle system is powered with a 103kW 2.5L Detroit Diesel engine which operates with a fuel blend consisting of ultra-low-sulfur diesel and biodiesel (35%). Lower emissions are inherently achieved by the use of biodiesel. Additionally, the engine was fitted with a series of aftertreatment devices in an effort to achieve the low emissions standards. Vehicle testing has shown a gasoline-equivalent fuel economy improvement of approximately 22%, a reduction in greenhouse gas emissions by approximately 38%, and meeting or exceeding stock emissions numbers in all other categories through the use of an advanced catalyst and control strategy.

Stochastic Preignition (SPI) is an abnormal combustion event that occurs in a turbocharged engine and can lead to the loss in fuel economy and engine hardware damage, and in turn result in customer dissatisfaction. It is a significant limiting factor on the use and continued downsizing of turbocharged spark ignited direct injection (SIDI) gasoline engines. Understanding and mitigating all the factors that cause and influence the rate and severity of SPI occurrence are of critical importance to the engine’s continued use and fuel economy improvements for future designs. Previous studies have shown that the heavy molecular weight components of the fuel formulations are one factor that influences the rate of SPI from a turbocharged SIDI gasoline engine. All the previous studies have involved analyzing the fuel’s petroleum hydrocarbon chemistry, but not specifically the additives that are put in the fuel to protect and clean the internal components over the life of the engine.

Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution systems used for transportation of fuel from refineries. They are also used to buffer the potential organic acids present in an ethanol blended fuel to enhance storage stability. The impact of the types of inhibitors on spark-ignition engine fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the corrosion inhibitors to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a survey of corrosion inhibitors and how they vary in concentration in the final blended fuel, specifically E85 (Ethanol Fuel Blends); and to show how variation in concentration of components of CIs and detergents impact intake valve deposit formation.

A gasoline’s chemical composition impacts a vehicle’s sooting tendency and therefore has been the subject of numerous emissions studies. From these studies, several mathematical correlation equations have been developed to predict a gasoline’s sooting tendency in modern spark-ignited internal combustion engine vehicles. This paper reviews the recently developed predictive tool methods and summarizes five years of global market fuel survey data to characterize gasoline sooting tendency trends around the world. Additionally, the paper will evaluate and suggest changes to the predictive methods to improve emissions correlations.

Classic, hot-spot induced pre-ignition is a phenomenon that has been observed in gasoline spark ignited engines over the past 60-70 years. With the development of turbocharged, direct-injected (DI) gasoline engines, a new pre-ignition phenomenon occurring at low engine speeds and high loads has been encountered. Termed Stochastic Pre-ignition (SPI), it has become a significant issue to address in allowing for the full potential of gasoline turbo DI technology to improve powertrain efficiency. Many researchers are studying all aspects of the causes of Stochastic Pre-ignition, including causes by oil, fuel and engine hardware systems. The focus of this specific research was to study the relationship of fuel octane and volatility to Stochastic Pre-ignition behavior utilizing a GM 2.0L Gasoline Turbocharged DI engine (LHU).

Stochastic or Low-Speed Preignition (SPI or LSPI) is an undesirable abnormal combustion phenomenon encountered in spark-ignition engines. It is characterized by very early heat release and high cylinder pressure and can cause knock, noise and ultimately engine damage. Much of the focus on mitigating SPI has been directed towards the engine oil formulation, leading to the emergence of the Sequence IX test and second-generation GM dexos® oil requirements. Engine design, calibration and fuels also contribute to the prevalence of SPI. As part of a recently completed research consortium, a series of engine tests were completed to determine the impact of fuel composition on SPI frequency. The fuel blends had varying levels of paraffins, olefins, aromatics and ethanol.

In this multi-phase study, fuel and lubricant effects on stochastic preignition (SPI) were examined. First, the behavior of fuels for which SPI data had previously been collected were characterized in terms of their combustion and emissions behavior, and correlations between these characteristics and their SPI behavior were examined. Second, new SPI data was collected for a matrix of fuels that was constructed to test and confirm hypotheses that resulted from interpretation of the earlier data in the study and from data in open literature. Specifically, the extent to which the presence of heavy components in the fuel affected SPI propensity, and the extent to which flame initiation propensity affected SPI propensity, were examined. Finally, the interaction of fuels with lubricants expected to exhibit a range of SPI propensities was examined.

In order to further understand the sequence of events leading to stochastic preignition in a spark-ignition engine, a methodology previously developed by the authors was used to evaluate the propensity of a wide range of fuels to establishing propagating flames under conditions representative of those at which stochastic preignition (SPI) occurs. The fuel matrix included single component hydrocarbons, binary mixtures, and real fuel blends. The propensity of each fuel to establish a flame was correlated to multiple fuel properties and shown to exhibit consistent blending behaviors. No single parameter strongly predicted a fuel’s propensity to establish a flame, while multiple reactivity-based parameters exhibited moderate correlation. A two-stage model of the flame establishment process was developed to interpret and explain these results.

Several oxygenates have been proposed and tested for use with or as diesel fuel. This paper examines two such oxygenates, CETANER™ and dimethyl ether (DME), partially or wholly produced by Air Products and Chemicals, Inc's Liquid Phase Technology. In previous studies on a single cylinder compression ignition engine and a Volkswagen TDI four cylinder engine, significant reductions in particulate matter emissions were observed with blends of CETANER™ in diesel fuel. In this study, experiments were performed on a multi-cylinder Navistar 7.3L Turbodiesel engine confirmed and extended the observations from the earlier studies. This is an important step in not only showing that the fuel does perform on each type of engine in similar fashion, but also in showing that DME and its derivatives can give consistent, significant results in lowering emissions. The oxygenated fuels were blended to achieve a net addition of 2 wt.% oxygen in the blended fuel.