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Deep charge and discharge cycling of 24 Volt battery strings composed of two 12 Volt VRLA batteries wired in series affects reliability and life expectancy. This is a matter of interest in vehicle power source applications. These cycles include those specific operational cases requiring the delivery of the full storage capacity during discharge. The concern here is related to applications where batteries serve as a primary power source and the energy content is an issue. It is a common practice for deep cycling a 24 volt battery string to simply add the specified limit voltages during charge and discharge for the individual 12 Volt batteries. In reality, the 12 Volt batteries have an inherent capacity variability and are not identical in their performance characteristics. The actual voltages of the individual 12 Volt batteries are not identical.

The heat generation rate of a lithium ion cell was estimated using a reversible heat generation rate equation. Because the equation is based on the energy conservation law, the influence of kinetically slow processes should be considered. In this analysis, the influence of kinetically slow processes is present but it is small within the domain of the test measurements. This approximation can be of significant usefulness for modeling the thermal response of single cells and multi-cell batteries.