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From the energy security and environment standpoint, the biodiesel fuels derived from vegetable oils or animal fats appear to be promising alternative to fossil diesel. Although the engine experiments prove their viability, the scientific data base for characterizing biodiesel combustion is limited. Detailed studies on the characterization of biodiesel fuels and their effects on fundamental engine processes like droplet evaporation and combustion are essential. The present study evaluates the useful thermo-physical properties and droplet evaporation characteristics of biodiesel fuels. The droplet evaporation measurements are carried out using suspended droplet experiments on five biodiesel fuels of Indian origin viz. jatropha, pongamia (karanja), neem, mahua and palm. The droplet evaporation rates of these fuels are related to properties such as binary diffusivity and molecular weight, which in turn depend on their fatty acid composition.

The replacement of fossil diesel with neat biodiesel in a compression ignition engine has advantage in lowering unburned hydrocarbon, carbon monoxide and smoke emissions. However, the injection advance experienced with biodiesel fuel with respect to diesel injection setting increases oxides of nitrogen emission. In this study, the biodiesel-NO control is attempted using charge and fuel modification strategies with retarded injection timing. The experiments are performed at maximum torque speed and higher loads viz. from 60% up to full load conditions maintaining same power between diesel and biodiesel while retarding the timing of injection by 3 deg. crank angle. The charge and fuel modifications are done by recycling 5% by volume of exhaust gas to the fresh charge and 10% by volume of methanol to Karanja biodiesel.

Biodiesel is an emerging alternative to fossil diesel for use in compression ignition engines. From environmental standpoint, an increase in nitric oxide (NO) emission from biodiesel fueled engine has been a major concern. Several investigations suggest the role of unsaturated methyl ester as a contributor to biodiesel-NO penalty. The chemical simplicity of biodiesel compared to fossil diesel makes their composition effects amenable to a systematic analysis. In this study, the effects of saturated palm and unsaturated karanja (Pongamia pinnata) biodiesels and their blends (Bio-mix) on compression ignition engine performance, combustion and NO emission are investigated. The combustion and emission characteristics of these fuels are compared with fossil diesel that the neat biodiesel fuels result in improved exhaust emissions except NO with a penalty in fuel economy.