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Very high pressures for injecting gasoline in internal combustion (i.c.) engines are recently explored for improving the air/fuel mixing process in order to control unburned hydrocarbons (UBHC) and particulate matter emissions such as for investigating new combustion concepts. The challenge remains the improvement of the spray parameters in terms of atomization, smaller droplets and their spread in the combustion chamber in order to enhance the combustion efficiency. In this framework, the raise of the injection pressure plays a key role in GDI engines for the trade-off of CO2 vs other pollutant emissions. This study aims contributing to the knowledge of the physical phenomena and mechanisms occurring when fuel is injected at ultra-high pressures for mapping and controlling the mixture formation.